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Reaction of some cyclicβ-triketones with diazomethane

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    2-Acetyl-1,3-cyclopentanedione reacts with diazomethane at the carbonyl group in the ring to give the 1(3)-O-methylderivative.

  2. 2.

    2-Acetyl-1,3-cyclohexanediones react with diazomethane predominantly at the acetyl keto group.

  3. 3.

    The 1(3)-O-methyl ether of 5-phenyl-2-acetyl-1,3-cyclohexanedione reacts with diazomethane at the trigonal C(3) centers.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    A. A. Akhrem, A. M. Moiseenkov, F. A. Lakhvich & A. I. Poselenov

Authors
  1. A. A. Akhrem
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  2. A. M. Moiseenkov
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  3. F. A. Lakhvich
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  4. A. I. Poselenov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 143–147, January, 1972.

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Akhrem, A.A., Moiseenkov, A.M., Lakhvich, F.A. et al. Reaction of some cyclicβ-triketones with diazomethane. Russ Chem Bull 21, 128–131 (1972). https://doi.org/10.1007/BF00855670

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  • DOI: https://doi.org/10.1007/BF00855670

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