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Failure of sterically cross-linked polymers

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Abstract

A method is suggested for describing local long-term strength which is based on specific concepts about failure mechanisms of sterically cross-linked polymers. Microstructural characteristics of the material are used for a detailed description of the local failure process; from these one can go over to a damage macroparameter by use of the method proposed in [2]. A kinetic equation is obtained, from which simple formulas follow, for a number of cases, for determining time to failure as a function of the form of stressed state or the like. These formulas agree qualitatively with similar empirical relationships. A definition of the concept of local failure and a condition (criterion) for failure are given within the framework of the approach developed.

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Literature cited

  1. G. M. Bartenev and Yu. S. Zuev, Strength and Failure of Highly Elastic Materials [in Russian], Moscow-Leningrad (1964).

  2. S. K. Kanaun and A. I. Chudnovskii, Quasibrittle Failure of Metals [in Russian], Tr. TsKTI im. Polzunova, Leningrad, 19, 109 (1971).

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A. A. Zhdanov Leningrad State University. Translated from Mekhanika Polimerov, No. 4, pp. 612–620, July–August, 1972.

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Ul'tan, V.E., Chebanov, V.M. & Chudnovskii, A.I. Failure of sterically cross-linked polymers. Polymer Mechanics 8, 528–535 (1972). https://doi.org/10.1007/BF00855577

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  • DOI: https://doi.org/10.1007/BF00855577

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