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Peculiarities of epoxide polymers modified with polychlorodiphenyl

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Abstract

The effect of polychlorodiphenyl (a low-molecular plasticizer) on the dynamic mechanical characteristics of epoxide polymers, namely, their strength, creep, and water absorption, are studied over a wide temperature range. Modification with polychlorodiphenyl is found to increase the rigidity and decrease the molecular-group mobility of a polymer, which correlates with changes in the physicomechanical properties. The effect of polychlorodiphenyl, different than that of other plasticizers, is explained here by a closer intermolecular coupling and a smaller free volume within the system, as has been confirmed by results of infrared spectrometry, as well as by measurements of density and sorptive properties.

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Authors
  1. V. G. Khozin
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  2. R. M. Sultanaev
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  3. N. S. Prokhorova
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Additional information

Institute of Structural Engineering, Kazan. Translated from Mekhanika Polimerov, No. 2, pp. 218–223, March–April, 1975.

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Khozin, V.G., Sultanaev, R.M. & Prokhorova, N.S. Peculiarities of epoxide polymers modified with polychlorodiphenyl. Polymer Mechanics 11, 187–191 (1975). https://doi.org/10.1007/BF00854719

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  • DOI: https://doi.org/10.1007/BF00854719

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