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Vibrational spectra and certain properties of anhydrous aluminum perchlorate

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Anhydrous aluminum perchlorate is a crystalline substance with a hexagonal lattice. According to the data of the vibrational spectra, Al(ClO4)3 belongs to the class of covalent perchlorates with bidentate ClO4 groups.

  2. 2.

    Aluminum perchlorate, without melting, decomposes in the interval 150–450° to A12O3, Cl2, and O2, with intermediate formation of oxyperchlorates Al2O(ClO4)4 and AlOClO4.

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Literature cited

  1. G. G. Morvin and L. B. Woolaver, Industr. and Engng. Chem. Anal. Ed.,17, 474 (1945).

    Google Scholar 

  2. M. M. Bel'kova, L. A. Alekseenko, and V. V. Serebrennikov, Transactions of Tomsk University. Problems of Chemistry [in Russian], No. 3 (1965), p. 146.

    Google Scholar 

  3. M. M. Bel'kova, L. A. Alekseenko, and V. V. Serebrennikov, Zh. Fiz. Khimii,40, 2546 (1966).

    Google Scholar 

  4. E. G. Hackenber and H. Ulich, Z. Anorgan. und Allgem. Chem.,243, 99 (1939).

    Google Scholar 

  5. G. Franz, J. Inorg. and Nucl. Chem.,25, 737 (1963).

    Google Scholar 

  6. Z. K. Nikitina, A. I. Karelin, and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 723 (1973).

  7. V. M. Vdovenko, A. I. Skoblo, and D. N. Suglobov, Radiokhimiya,6, 677 (1964).

    Google Scholar 

  8. D. G. Lemesheva and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1877 (1969).

  9. D. G. Lemesheva, Dissertation [in Russian], Moscow (1971).

  10. B. J. Hathaway and A. E. Underhill, J. Chem. Soc., 3091 (1961).

  11. F. A. Cotton and D. L. Weaver, J. Amer. Chem. Soc.,87, 4189 (1965).

    Google Scholar 

  12. L. E. Moore, R. S. Gayhart, and W. E. Bull, J. Inorg. and Nucl. Chem.,26, 896 (1964).

    Google Scholar 

  13. H. C. Clark and R. J. O'Brien, Inorg. Chem.,2, 740 (1963).

    Google Scholar 

  14. W. R. McWhinnie, J. Inorg. and Nucl. Chem.,26, 21 (1964).

    Google Scholar 

  15. V. M. Vdovenko, L. G. Mashirov, and D. N. Suglobov, Radiokhimiya,6, 299 (1964).

    Google Scholar 

  16. A. E. Wikenden and R. A. Krause, Inorg. Chem.,4, 404 (1965).

    Google Scholar 

  17. F. Madaule-Aubry and J. M. Bown, Acta Crystallogr.B24, 745 (1968).

    Google Scholar 

  18. P. A. Giguere and R. Savoie, Canad. J. Chem.,40, 495 (1962).

    Google Scholar 

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Authors and Affiliations

  1. Institute of New Chemical Problems, Academy of Sciences of the USSR, USSR

    Z. K. Nikitina, A. I. Karelin & V. Ya. Rosolovskii

Authors
  1. Z. K. Nikitina
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  2. A. I. Karelin
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  3. V. Ya. Rosolovskii
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Translated from Izvestiya Akademil Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 971–974, May, 1973.

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Nikitina, Z.K., Karelin, A.I. & Rosolovskii, V.Y. Vibrational spectra and certain properties of anhydrous aluminum perchlorate. Russ Chem Bull 22, 937–939 (1973). https://doi.org/10.1007/BF00854226

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  • DOI: https://doi.org/10.1007/BF00854226

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