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Rietveld refinement and electrical properties of cadmium lithium phosphate

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Abstract

Cadmium lithium phosphate, LiCdPO4, has been prepared by the solid state reaction method and characterized by X-ray powder diffraction at room temperature. This compound crystallizes in the orthorhombic system with Pnma space group. Vibrational study by means of Raman spectroscopy confirms the existence of the (PO4)3− functional group. The electrical properties have been investigated in the frequency range 209 Hz–1 MHz and temperature range 584–686 K. Experimental measurements of ac conductivity were fitted by the Jonscher’s universal power law: \({\sigma _{ac}}={\sigma _{dc}}+A{\omega ^n}.\)

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Acknowledgements

This work is financially supported by the Ministry of Higher Education and Scientific Research of Tunisia.

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Authors and Affiliations

  1. Laboratory of Spectroscopic Characterization and Optic of Materials, Faculty of Sciences, University of Sfax, B.P. 1171, 3000, Sfax, Tunisia

    Amal Djemal, Bassem Louati & Kamel Guidara

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  1. Amal Djemal
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  2. Bassem Louati
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  3. Kamel Guidara
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Correspondence to Amal Djemal.

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Djemal, A., Louati, B. & Guidara, K. Rietveld refinement and electrical properties of cadmium lithium phosphate. J Mater Sci: Mater Electron 28, 13806–13813 (2017). https://doi.org/10.1007/s10854-017-7226-6

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  • DOI: https://doi.org/10.1007/s10854-017-7226-6

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