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Complexing capacity of bis(trinitromethyl)mercury

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Bis(trinitromethyl)mercury forms 1∶1 complexes, in which the covalent HgC bond is retained, with various compounds that function as electron donors.

  2. 2.

    The complexes of bis(trinitromethyl)mercury with nitroalkanes and secondary nitramines were obtained and characterized.

  3. 3.

    The reaction of bis(trinitromethyl)mercury with pyridine gives the dipyridylmercuronium salt of nitroform.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    A. L. Fridman, T. N. Ivshina, V. P. Ivshin, V. A. Tartakovskii & S. S. Novikov

Authors
  1. A. L. Fridman
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  2. T. N. Ivshina
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  3. V. P. Ivshin
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  4. V. A. Tartakovskii
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  5. S. S. Novikov
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Additional information

See [1, 2] for the preliminary communication.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2279–2284, October, 1971.

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Fridman, A.L., Ivshina, T.N., Ivshin, V.P. et al. Complexing capacity of bis(trinitromethyl)mercury. Russ Chem Bull 20, 2151–2154 (1971). https://doi.org/10.1007/BF00851269

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  • DOI: https://doi.org/10.1007/BF00851269

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