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Highly unsaturated polymers Communication 17. Synthesis of mono- and di-1-buten-3-ynyl derivatives of benzene and their oxidative condensation

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A method is proposed for the synthesis of highly unsaturated monomeric and polymeric compounds with alternating double and triple bonds.

  2. 2.

    Some mono- and di-1-buten-3-ynyl derivatives of benzene were synthesized as monomers.

  3. 3.

    In the IR spectra of the compounds with two double and two triple bonds in conjugation the intensity of the triple bond band is very greatly increased.

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Authors and Affiliations

  1. Institute of Chemical Kinetics and Combustion, Siberian Division, Academy of Sciences of the USSR, USSR

    I. L. Kotlyarevskii, M. I. Bardamova & T. G. Shishmakova

Authors
  1. I. L. Kotlyarevskii
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  2. M. I. Bardamova
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  3. T. G. Shishmakova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 909–914, May, 1966.

The authors thank E. E. Zaev for determining the NMR spectrum.

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Kotlyarevskii, I.L., Bardamova, M.I. & Shishmakova, T.G. Highly unsaturated polymers Communication 17. Synthesis of mono- and di-1-buten-3-ynyl derivatives of benzene and their oxidative condensation. Russ Chem Bull 15, 867–871 (1966). https://doi.org/10.1007/BF00849389

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  • DOI: https://doi.org/10.1007/BF00849389

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