Conclusions
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1.
An investigation was made of the reactions of diazoacetic ester with the branched alkenes 2,3,3-trimethyl-1-butene, 4-propyl-3-heptene, and 3-isopropyl-2,4-dimethyl-2-pentene.
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2.
In the synthesis of alcohols from ethyl 2-t-butyl-2-methylcyclopropanecarboxylate and ethyl 3-ethyl-, 2,2-dipropylcyclopropanecarboxylate opening of the cyclopropane ring occurs to some extent under the action of CH3MgCl under the conditions of the Grignard reaction.
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A. P. Meshcheryakov and I. E. Dolgii, Izv. AN SSSR. Otd. khim.n.,1960, 931.
A. P. Meshcheryakov and I. E. Dolgii, Izv. AN SSSR. Otd. khim.n.,1960, 1874.
L. A. Chugaev, Selected Works [in Russian], Izd. AN SSSR,2, Moscow (1954).
I. E. Dolgii and A. P. Meshcheryakov, Izv. AN SSSR. Otd. khim. n.,1963, 572.
M. S. Kaharasch, H. Mz. Bay, and W. H. Urry, J. Organ. Chem.,10, 401 (1945).
I. H. T. Brook, Frans. Faraday Soc.,53, No. 3, 327 (1957).
W. E. Doering, R. G. Buttery, R. G. Laughlin, and N. Chaudhuri, J. Amer. Chem. Soc.,78, 3224 (1956).
W. E. Doering and L. H. Knox, J. Amer. Chem. Soc.,78, 4947 (1956).
W. E. Doering and H. Prinzbach, Tetrahedron,6, No. 1, 24 (1959).
A. P. Meshcheryakov and I. E. Dolgii, Izv. AN SSSR. Otd. khim.n.,1961, 496.
R. D. Obolentsev, Physical Constants of Hydrocarbons of Liquid Fuels and Oils [in Russian], Gostoptekhizdat (1953).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1235–1240, July, 1966.
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Meshcheryakov, A.P., Dolgii, I.E., Manakov, M.N. et al. Reactions of diazoacetic ester with branched alkenes. Russ Chem Bull 15, 1186–1190 (1966). https://doi.org/10.1007/BF00847760
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DOI: https://doi.org/10.1007/BF00847760