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An investigation of the structure of salts of 1,1-dinitroalkanes and trinitromethane by spectral methods

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

An investigation of the infrared spectra showed that the salts (potassium, sodium, ammonium, and lithium) of 1,1-dinitroalkanes and trinitromethane have three absorption bands: ∼1480, ∼1210, and ∼1120 cm−1. The infrared spectra do not contain absorption bands characteristic of the C=N double bond or an uncharged nitro group. Therefore, it is confirmed that salts of 1,1-dinitroalkanes and trinitromethane do not contain a C=N bond, and that all the nitro groups are equivalent and participate equally in the formation of the anion.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Academy of Sciences, USSR

    V. I. Slovetskii, S. A. Shevelev, V. I. Erashko, A. A. Fainzil'berg & S. S. Novikov

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  1. V. I. Slovetskii
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  2. S. A. Shevelev
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  3. V. I. Erashko
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  4. A. A. Fainzil'berg
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  5. S. S. Novikov
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Slovetskii, V.I., Shevelev, S.A., Erashko, V.I. et al. An investigation of the structure of salts of 1,1-dinitroalkanes and trinitromethane by spectral methods. Russ Chem Bull 12, 49–54 (1963). https://doi.org/10.1007/BF00846948

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  • DOI: https://doi.org/10.1007/BF00846948

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