Abstract
By reaction of several N-phenyl-benzamidrazones with SO2F2 2-phenyl-2,5-dihydro-1,2,3,5-thiatriazole-1,1-dioxides2 a–c are formed. By reaction of N,N-diethyl-N′-chlorosulfonyl-chloroformamidine8 with hydrazines the corresponding 4-diethylamino-substituted derivatives9 a–d are obtained. Methylation of2 b yields two isomeric products5 and6, whereas by methylation of9 d only one product9 b is obtained.
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Literatur
Teil der Dissertation vonKosma P., Technische Universität Wien, 1980.
Knollmüller M.,Kosma P., Monatsh. Chem., im Druck.
Reimlinger H., Lingier W. R. F., Vandewalle J. J. M., Chem. Ber.104, 639 (1971).
Traube W., Reubke E., Ber. dtsch. chem. Ges.56, 1656 (1923).
Busch M., Ruppenthal R., ibid.43, 3001 (1910).
Engelhardt R., J. prakt. Chem.54, 143 (1896).
Huisgen R., Grashey R., Aufderhaar E., Kunz R., Chem. Ber.98, 642 (1965).
Wamhoff H., Sohár P., Chem. Ber.104, 3510 (1971).
Markovskii L. N., Shermolovich Yu. G., Shevchenko V. I., Zh. Org. Khim.1973, 9 (3), 633.
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Knollmüller, M., Kosma, P. Über die Synthese von Dihydro-1,2,3,5-thiatriazol-1,1-dioxiden, 2. Mitt.. Monatsh Chem 116, 1321–1327 (1985). https://doi.org/10.1007/BF00811103
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DOI: https://doi.org/10.1007/BF00811103