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LiFe3+(Se2O5)2 and its structure relationships toMe 2+(Se2O5) compounds

LiFe3+(Se2O5)2 und Strukturbeziehungen zuMe 2+(Se2O5)-Verbindungen

  • Anorganische Und Physikalische Chemie
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Summary

LiFe3+(Se2O5)2 was obtained by hydrothermal synthesis and the structure was investigated by single crystal X-ray diffraction methods:a=5.987(2)Å,b=6.760(2)Å,c=10.295(3)Å,V=416.66Å3;Z=2, space group Pnc2,R=0.028,R w=0.028 for 2002 independent reflections (sinϑ/λ≤0.90Å−1). The crystal structure of LiFe3+(Se2O5)2 is closely related with that ofMe 2+(Se2O5) compounds (Me=Mn, Co, Zn).

Zusammenfassung

Die hydrothermal dargestellte Verbindung LiFe3+(Se2O5)2 wurde mittels Einkristallbeugungsmethoden untersucht:a=5.987(2)Å,b=6.760(2)Å,c=10.295(3)Å,V=416.66Å3;Z=2, Raumgruppe Pnc2,R=0.028,R w=0.028 für 2002 unabhängige Reflexe (sin ϑ/λ≤0.90Å−1). Die Kristallstruktur von LiFe3+(Se2O5)2 zeigt eine enge Verwandtschaft mit der vonMe 2+(Se2O5)-Verbindungen (Me=Mn, Co, Zn).

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Authors and Affiliations

  1. Institut für Mineralogie und Kristallographie, Universität Wien, A-1010, Wien, Austria

    Gerald Giester

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  1. Gerald Giester
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Giester, G. LiFe3+(Se2O5)2 and its structure relationships toMe 2+(Se2O5) compounds. Monatsh Chem 124, 1107–1113 (1993). https://doi.org/10.1007/BF00810018

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  • DOI: https://doi.org/10.1007/BF00810018

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