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Complex [MoO2(L)(CH3OH)] (L2- = 3-methoxysalicylidenemonoethanolimine anion): Synthesis, crystal and molecular structures

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Abstract

The complex [MoO2(L)(CH3OH)] (where L2- is 3-methoxysalicylidenemonoethanolimine anion) has been prepared and structurally characterized by X-ray diffraction. The molybdenum atom has an octahedral coordination to two ligands in cis-positions to each other, two oxygen atoms, the nitrogen atom of the tridentate bis(chelate) L2- ligand, and also the oxygen atom of methanol. Strong O-H⋯O hydrogen bonds (O⋯O, 2.598 Å) link pairs of molecules into centrosymmetric pseudo-dimers.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    V. S. Sergienko, Yu. N. Mikhailov & M. D. Surazhskaya

  2. Dal’ East Ukrainian National University, Molodezhnyi kvartal 20a, Lugansk, 91034, Ukraine

    V. L. Abramenko

Authors
  1. V. S. Sergienko
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  2. V. L. Abramenko
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  3. Yu. N. Mikhailov
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  4. M. D. Surazhskaya
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Correspondence to V. S. Sergienko.

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Original Russian Text © V.S. Sergienko, V.L. Abramenko, Yu.N. Mikhailov, M.D. Surazhskaya, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 11, pp. 1503–1506.

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Sergienko, V.S., Abramenko, V.L., Mikhailov, Y.N. et al. Complex [MoO2(L)(CH3OH)] (L2- = 3-methoxysalicylidenemonoethanolimine anion): Synthesis, crystal and molecular structures. Russ. J. Inorg. Chem. 59, 1259–1262 (2014). https://doi.org/10.1134/S0036023614110205

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  • DOI: https://doi.org/10.1134/S0036023614110205

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