Abstract
A simple isotherm equation is derived for the adsorption of an organic component onto activated carbon in presence of water vapour. The theoretical results are compared with experimental data for toluene-water vapour-activated carbon, which were published byRipperger andGermerdonk [10].
Zusammenfassung
Es wird eine einfache Adsorptionsisotherme abgeleitet, welche die gleichzeitige Adsorption eines organischen Stoffes und Wasser an Aktivkohle beschreibt. Die theoretischen Ergebnisse werden mit experimentellen Resultaten vonRipperger undGermerdonk [10] für Toluol-Wasser-Aktivkohle verglichen.
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Abbreviations
- a i :
-
adsorbate concentration in adsorbent, kg/kg of carbon
- a 0i :
-
monolayer capacity, kg/kg of carbon
- b i :
-
kinetic parameter of theLangmuir equation
- E j :
-
adsorption energy in thej-th layer
- i :
-
i-th component (1 — water vapour, 2 — organic compound)
- j :
-
j-th layer
- m :
-
number of layers
- n :
-
number of adsorbed components
- p :
-
partial pressure, Pa
- p*:
-
saturation partial pressure, Pa
- p C :
-
water vapour partial pressure at begining of capillary condensation, Pa
- ϑ:
-
surface coverage
References
Grant RJ, Manes M (1966) Ind Eng Chem Fund 5 490
Myers AL, Prausnitz JM (1965) AIChE J 11: 1216
Suwanayuen S, Danner RP (1980) AIChE J 26: 76
Protorzhinsky IV, Serpinova EN (1970) Trudy MKHTI im Mendeleeva 65: 79
Kovalskaya AP, Subbotin AI (1977) Prom Sanit Ochistka Gazov 3: 13
Petrova NI, Nikolaev KM (1982) Zh Prikl Khim 55: 1517
Petrova NI, Nikolaev KM (1982) Zh Prikl Khim 55: 1521
Dubinin MM,Kutkov VS,Larin AV,Nikolaev KM,Polyakov NS (1983) Izv Akad Nauk SSSR Ser Khim: 1231
Petrova NI, Nikolaev KM (1982) Zh Prikl Khim 55: 2089
Ripperger S, Germerdonk R (1983) Germ Chem Eng 6: 249
Takeuchi Y, Furuya E (1983) Prediction of the breakthrough in solvent recovery in an activated carbon bed. In:Myers AL, Belford G (eds) Fundamentals of adsorption conference. United Engineering Trustees, New York, p 629
Grant RJ, Joyce RS, Urbanic JE (1983) The effect of relative humidity on the adsorption of water-immiscible organic vapors on activated carbon, In:Myers AL, Belford G (eds) Fundamentals of adsorption conference. United Engineering Trustees, New York, p 219
Dubinin MM, Serpinsky VV (1981) Carbon 19: 402
Dubinin MM (1981) Izv Akad Nauk SSR Ser Khim: 9
Manes M (1983) Estimation of the effect of humidity on the adsorption onto activated carbon of the vapors of water-immiscible organic liquids, In:Myers AL, Belford G (eds) Fundamentals of adsorption conference. United Engineering Trustees, New York, p 335
Matsumura Y, Yamabe K, Takahashi H (1985) Carbon 23: 263
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Jędrzejak, A., Jabłoński, M. Prediction of adsorption of organic component and water vapour mixture onto activated carbon. Monatsh Chem 119, 187–194 (1988). https://doi.org/10.1007/BF00809593
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DOI: https://doi.org/10.1007/BF00809593