Abstract
Preferred conformations of some azaspiran systems substituted with large groups at the nitrogen atoms were established by UV absorption spectroscopy. These groups prohibit the inversion at nitrogen, as was deduced from the1H NMR spectra.
Similar content being viewed by others
Literatur
Smoliński S., Rys B., Monatsh. Chem.110, 279 (1979).
Speckamp W. N., Pandit U. K., Korver P. K., van der Haak P. J., Huisman H. O., Tetrahedron22, 2413 (1966).
Perales A., Garcia-Blanco S., Acta Crystallogr.B33, 3169 (1977).
Smoliński S., Nowicka J., Mokrosz J., Jamrozik M., Jaworski M., Wiekiera E., Tetrahedron33, 1219 (1977).
Stetter H., Stark H., Chem. Ber.86, 197 (1956).
Bleier L., Chem. Ber.32, 1826 (1899).
Hinsberg O., Strupler A., Ann.287, 226 (1895).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Smoliński, S., Kubaszek, M. Synthese und Konformation einiger Azaspirane mit Alkyl-bzw. Aryl-Sulfonamid-Gruppen. Monatsh Chem 115, 79–86 (1984). https://doi.org/10.1007/BF00798423
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00798423