Conclusions
X-ray phase analyses and measurements of the emfs of concentration galvanic cells have demonstrated that Mn3Si and Mn5Si3 are the only compounds coexisting in the binary system Mn-Si at silicon contents ranging from 25 to 37.5 at. %; Mn5Si2 does not form under these conditions. The isobaricisothermal potential, heat, and entropy of formation of the suicide Mn3Si have been redetermined.
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Translated from Poroshkovaya Metallurgiya, No. 8(224), pp. 67–70, August, 1981.
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Lukashenko, G.M., Sidorko, V.R. & Kotur, B.Y. Phase constitution and thermodynamic properties of alloys of the Mn-Si system in the range from 25 to 37.5 at. %Si. Powder Metall Met Ceram 20, 571–574 (1981). https://doi.org/10.1007/BF00791707
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DOI: https://doi.org/10.1007/BF00791707