Conclusions
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1.
Under conditions of detonation of mixed compounds, the effect on the UDD synthesis of the initial molecular structure of the organic additives manifests itself above all through the capability to undergo in the earlier loading stages a transformation with the separation of free carbon.
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2.
The dispersity of the diamond phase formed during the decomposition of the additives strongly depends on the thermodynamic parameters achieved in the detonation wave.
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Literature Cited
V. F. Anisichkin, I. Yu. Mal'kov and V. M. Titov, “Synthesis of diamonds by dynamic loading of organic materials”, Dokl. Akad. Nauk SSSR,303, No. 3, 625 (1988).
V. M. Titov, V. F. Anisichkin and I. Yu. Mal'kov, Diamond Synthesis from Dynamically Loaded Organic Matter: Shock Compression of Condensed Matter, New York (1990).
R. F. Trunin, M. V. Zhernokletov et al., “Dynamic compressibility of saturated and aromatic hydrocarbons”, Proc. 4th All-Union Conf. on Detonation, Chernogolovka, Vol. 1, 166 (1988).
L. V. Babare, A. N. Dremin et al., “Polymerization of difficultly polymerizable organic compounds during shock compression”, Fiz. Goreniya Vzryva,5, No. 4 (1969).
V. V. Yakushev, A. N. Dremin et al., “Physical properties and transformation of nitrobenzene at dynamic pressure to 30 Gpa”, Fiz. Goreniya Vzryva,15, No. 4 (1979).
R. D. Dick, “Shock wave compression of benzene, carbon disulfide, carbon tetrachloride and liquid nitrogen”, J. Chem. Phys.,52, No. 12, 6021, (1970).
V. M. Titov, V. F. Anisichkin and I. Yu Mal'kov, “Investigation of the ultra-dispersed diamond synthesis process in detonation waves”, Fiz. Goreniya Vzryva,25, No. 3, 117 (1989).
A. P. Ershov, A. L. Kupershtokh and V. N. Kolomiichuk, “Formation of frontal structures during explosions”, Pis'm. Zh. Tekh. Fiz.,16, No. 3, 42 (1990).
B. N. Kondrikov and V. N. Shapoval, “Problems in the condensed system theory”, Tr. Mosk. Khim.-Tekhnol. Inst.,112, 134 (1980).
I. K. Kikoin, ed., Tables of Physical Quantities: Handbook [in Russian], Atomizdat, Moscow (1976).
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Novosibirsk. Translated from Fizika Goreniya i Vzryva, Vol. 27, No. 5, pp. 136–140, September–October, 1991.
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Mal'kov, I.Y. Formation of ultra-dispersed diamond phase of carbon under conditions of detonation of heterogeneous mixture compounds. Combust Explos Shock Waves 27, 641–644 (1991). https://doi.org/10.1007/BF00784958
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DOI: https://doi.org/10.1007/BF00784958