Conclusions
-
1.
Quantitative analysis of chromatograms by internal normalization of the products of the width of the peak by the retention time, without the introduction of correction coefficients, is possible only with a practically constant value of the efficiency of the column, calculated from the parameters of the different peaks. In the case of the analysis of braod fractions, when the efficiency varies considerably with a transition from the first component to the last, the results of a calculation employing normalization of the products h · tR can only be in the nature of an estimate.
-
2.
The value of the correction coefficient, in a calculation using normalization of the products h · tR, is equal to the square root of a height equivalent to a theoretical plate.
Similar content being viewed by others
Literature cited
L. Onkiehong, Gas Chromatography (editor R. P. W. Scott), Buttersworth, London (1960), p. 7.
A. E. Messner, D. M. Rosie, and P. A. Argabright, Analyt. Chem.,29, 1164 (1957).
A. A. Zhukhovitskii and N. M. Turkel'taub, Gas Chromatography [in Russian], Gostoptekhizdat (1962).
K. A. Gol'berg and M. S. Vigdergauz, Course in Gas Chromatography [in Russian], Khimiya (1967).
K. K. Carroll, Nature,191, 377 (1961).
J. C. Bartlett and D. M. Smith, Can. J. Chem.,38, 2057 (1960).
H. Stickler and E. J. Kovats, Chromatog.,8, 289 (1962).
D. M. Smith and I. C. Bartlet, Nature,191, 688 (1961).
S. Polezzo and M. Taramasso, La Chimica e l'Industria,44, 33 (1962).
B. D. Blaustein and G. M. Feldman, Analyt. Chem.,36, No. 1, 65 (1964).
M. P. Ivanova, V. I. Petrova, and R. I. Sidorov,9, No. 4 (1969).
R. L. Martin and I. C. Winters, Analyt. Chem.,35, 1930 (1963).
M. S. Vigdergauz and V. V. Pomazanov, in: Advances in Gas Chromatography [in Russian], Izd. Vsesoyuznogo Khimicheskogo Obshchestva im. D. I. Mendeleeva, No. 1 (1969), p. 61.
M. S. Vigdergauz and V. I. Semkin, Neftekhimiya,9, No. 3, 470 (1969).
Additional information
Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 8, pp. 53–56, August, 1971.
Rights and permissions
About this article
Cite this article
Bogdanchikov, A.I., Vigdergauz, M.S. Quantitative interpretation of the chromatograms of multicomponent mixtures. Chem Technol Fuels Oils 7, 625–628 (1971). https://doi.org/10.1007/BF00714040
Issue Date:
DOI: https://doi.org/10.1007/BF00714040