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Structure of hydrocarbon radicals in zinc dialkyldithiophosphates

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Chemistry and Technology of Fuels and Oils Aims and scope

Conclusions

  1. 1.

    A study has been made of the infrared absorption spectra of dialkyldithiophosphoric acids containing hydrocarbon radicals of different structure.

  2. 2.

    The valence vibrations of the bonds P= S, P-S, and C-O-(P) correspond to the frequency ranges 651–671, 507–550, and 967–1045 cm−1.

  3. 3.

    The structure of the hydrocarbon radicals has an effect on the position of the absorption bands P= S, P-S, and C -O-(P) in the spectrum.

  4. 4.

    The dependence of the frequencies of the bands vasCH3 and δsCH3 on the structure of the hydrocarbon radicals has been established.

  5. 5.

    The possibility of an analytical application of the region of valence vibration of the carbon structure (1100–1200 cm−1) has been demonstrated.

  6. 6.

    The spectral characteristic obtained for dialkyldithiophosphoric acids can be used to identify dialkyldithiophosphoric acids and, consequently, to establish the structure of the hydrocarbon radicals in zinc dialkyldithiophosphates.

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Literature cited

  1. K. I. Zimina, G. G. Kotova, P. I. Sanin, V. V. Sher, and G. N. Kuz'mina, Neftekhimiya,5, No. 4 (1965)

  2. K. I. Zimina, G. G. Kotova, V. V. Sher, G. N. Kuz'mina, and P. I. Sanin, Khim. i Tekhnol. Topliv i Masel, No. 1 (1966).

  3. K. I. Zimina, G. G. Kotova, P. I. Sanin, and V. V. Sher, Additives to Oils [in Russian], Khimiya (1966).

  4. G. G. Kotova, Additives to Oils [in Russian], Khimiya (1968).

  5. P. I. Sanin, V. V. Sher, I. F. Blagorovidov, N. G. Puchkov, M. S. Borovaya, et al., Additives to Oils [in Russian], Khimiya (1966).

  6. R. A. Bulgakova and R. R. Shagidullin, Izv. Akad. Nauk SSSR, Ser. Khim., No. 3 (1968).

  7. A. Pozefsky and H. Coggeshall, Analyt. Chem.,23, 1611 (1951).

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  8. K. Nakanisi, Infrared Spectra and the Structure of Organic Compounds [Russian translation], Mir (1965).

  9. L. Bellamy, The Infrared Spectra of Complex Molecules [Russian translation], Izd. Inostr. Lit. (1963).

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Authors and Affiliations

  1. All-Union Scientific-Research and Design Institute for Oil and Gas Refining and for Synthetic Liquid Fuel, USSR

    G. G. Kotova, M. F. Ulanova, N. S. Sosina, K. I. Zimina & M. M. Fialko

Authors
  1. G. G. Kotova
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  2. M. F. Ulanova
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  3. N. S. Sosina
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  4. K. I. Zimina
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  5. M. M. Fialko
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Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 8, pp. 31–33, August, 1971.

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Kotova, G.G., Ulanova, M.F., Sosina, N.S. et al. Structure of hydrocarbon radicals in zinc dialkyldithiophosphates. Chem Technol Fuels Oils 7, 599–601 (1971). https://doi.org/10.1007/BF00714034

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  • DOI: https://doi.org/10.1007/BF00714034

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