Abstract
(8-Quinolylthiomethyl)trimethoxy- and methyl(8-quinolylthiomethyl)dimethoxysilanes were synthesized and transformed into the corresponding organyltrifluoro- and methyldifluorosilanes. IR spectroscopy revealed the absence of N→Si donor-acceptor interaction in (8-quinolylthiomethyl)trifluorosilane and methyl(8-quinolylthiomethyl)difluorosilane. Transesterification of (8-quinolylthiomethyl)trimethoxysilane with triethanolamine yielded 1-(8-quinolylthiomethyl)silatrane; the crystal and molecular structures of the latter were determined by X-ray study.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 758–761, April, 1993.
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Voronkov, M.G., Chernov, N.F., Trofimova, O.M. et al. Si-substituted 8-quinolylthiomethylsilanes. Russ Chem Bull 42, 725–729 (1993). https://doi.org/10.1007/BF00704013
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DOI: https://doi.org/10.1007/BF00704013