Skip to main content
SpringerLink
Log in

ESR study of spin-adducts of trimethylaminoboryl radicals with fullerene C60

  • Organic Chemistry
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

It was established by ESR that trimethylaminoboryl radicals formed by UV irradiation of BH3NMe6w in the presence of di-tert-butyl peroxide in saturated benzene solutions of fullerene C60, add to fullerenes to give C60-BH2NMe3 spin-adducts. The latter undergo dimerization with a rate constant ofca. 2.5 · 106 L mol−1 s−1. A more prolonged photolysis of excess BH3NMe3 in a benzene solution of C60 results in multiple addition of the trimethylaminoboryl radicals to the fullerene to give stable radicals C60[BH2NMe3]n.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P. J. Krusic, E. Wasserman, B. A. Parkinson, B. Malone, E. R. Holler, Jr., P. N. Keizer, J. R. Morton, and K. F. Preston.J. Am. Chem. Soc., 1991,113, 6274.

    Google Scholar 

  2. P. J. Krusic, E. Wasserman, B. A. Parkinson, Jr., P. N. Keizer, J. R. Morton, and K. F. Preston,Science, 1991,254, 1183.

    Google Scholar 

  3. J. R. Morton, K. F. Preston, P. J. Krusic, S. A. Hill, and E. Wasserman.J. Am. Chem. Soc., 1992,114, 5454.

    Google Scholar 

  4. B. L. Tumanskii, V. V. Bashilov, S. P. Solodovnikov, and V. I. Sokolov,Izv. Akad. Nauk, Ser. Khim, 1992, 1457 [Bull. Acad. Sci., Div. Chem. Sci., 1992,41, 1140 (Engl. Transl.)].

    Google Scholar 

  5. B. L.Tumanskii, V. V. Bashilov, N. N. Bubnov, S. P. Solodovnikov, and V. I. Sokolov,Izv. Akad. Nauk, Ser. Khim, 1992, 1905 [Bull. Acad. Sci., Div. Chem. Sci., 1992,41, 1519 (Engl. Transl.)].

    Google Scholar 

  6. J. A. Baban, P. J. Marti, and B. P. Roberts.J. Chem. Soc. Perkin. Trans. II, 1985,11, 1723.

    Google Scholar 

  7. A. L. Buchachenko and A. M. Vasserman,Stabil'nye radikaly [stable radicals], Khimiya, Moscow, 1973, 58–72 (in Russian).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul.Vavilova, 117813, Moscow, Russian Federation

    B. L. Tumanskii, V. V. Bashilov, S. P. Soiodovnikov, N. N. Bubnov & V. I. Sokolav

  2. Weitsman Institute, Israel

    V. Ts. Kampel' & A. Warshawsky

Authors
  1. B. L. Tumanskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. V. Bashilov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. P. Soiodovnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. N. Bubnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. I. Sokolav
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. Ts. Kampel'
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. Warshawsky
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated fromIzyestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 673–675, April, 1994.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tumanskii, B.L., Bashilov, V.V., Soiodovnikov, S.P. et al. ESR study of spin-adducts of trimethylaminoboryl radicals with fullerene C60 . Russ Chem Bull 43, 624–626 (1994). https://doi.org/10.1007/BF00699836

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00699836

Key words

Search

Navigation