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1,3-Dipolar cycloaddition of diazocyclopropane to strained cycloalkenes and conjugated dienes to give spiro(1-pyrazoline-3,1′-cyclopropanes)

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Abstract

Polycyclic spiro(1-pyrazoline-3,1′-cyclopropanes) were obtained in 32–70 % yields by the reaction of diazocyclopropane generatedin situ with 2-methyltricyclo[3.2.1.02,4]oct-6-ene, spiro[2,4]hepta-4,6-diene dimer, benzvalene, spiro[2,3]hex-1-ene, methyl 1-methylcyclopropene-3-carboxylate, buta-1,3-diene, and 2-methylbuta-1,3-diene.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    Yu. V. Tomilov, E. V. Shulishov, G. P. Okonnishnikova & O. M. Nefedov

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  1. Yu. V. Tomilov
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  2. E. V. Shulishov
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  3. G. P. Okonnishnikova
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  4. O. M. Nefedov
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Additional information

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2199–2202, November, 1995.

This study was financially supported by the Russian Foundation for Basic Research (Grant No. 94-03-08902).

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Tomilov, Y.V., Shulishov, E.V., Okonnishnikova, G.P. et al. 1,3-Dipolar cycloaddition of diazocyclopropane to strained cycloalkenes and conjugated dienes to give spiro(1-pyrazoline-3,1′-cyclopropanes). Russ Chem Bull 44, 2105–2108 (1995). https://doi.org/10.1007/BF00696713

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  • DOI: https://doi.org/10.1007/BF00696713

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