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Direct writing of metal conductors with near-uv light

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Abstract

Deposition of micrometer-scale tungsten, molybdenum and platinum lines with the aid of the uv light from an argon-ion laser was investigated. Tungsten and molybdenum were deposited from their corresponding carbonyls and platinum from an acetylacetonate compound. High-quality metal conductors could be achieved for tungsten and platinum using a combined photolytic and pyrolytic, or “hybrid”, deposition scheme. The resistivity for these two deposited metals was approximately twice the bulk value. For molybdenum the deposition process was fast and dominated by the pyrolysis; the corresponding line resistivity was slightly higher than for the two other metals.

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References

  1. D.J. Ehrlich, R.M. Osgood, Jr., T.F. Deutsch: Appl. Phys. Lett.39, 957 (1981)

    Google Scholar 

  2. D.J. Ehrlich, R.M. Osgood, Jr., D.J. Silversmith, T.F. Deutsch: IEEE EDL-1, 101 (1980)

    Google Scholar 

  3. T. Cacouris, R.R. Krchnavek, H.H. Gilgen, R.M. Osgood, Jr., S. Kulick, J. Schoen: Technical Digest of 1985 Int. Electron. Device Meeting 1985 (IEEE, New York 1985) p. 594 or

    Google Scholar 

  4. R.R. Krchnavek, T. Cacouris, H.H. Gilgen, R.M. Osgood, Jr.: In Proc. of the Material Research Society Annual Meeting in Boston, 1985,Beam-Induced Chemical Processes, ed. by R.J. von Gutfeld, J.E. Greene, and H. Schlossberg (Material Research Society, Pittsburgh 1985) p. 179

    Google Scholar 

  5. I.P. Herman, B.M. McWilliams, F. Militsky, H.W. Chin, R.A. Hyde, L.L. Wood: In Proc of the Material Research Society Annual Meeting in Boston, 1983,Laser-Controlled Chemical Processing of Surfaces, ed. by A.W. Johnson, D.J. Ehrlich, and H.R. Schlossberg (North-Holland, New York 1984) Vol. 29. p. 29

    Google Scholar 

  6. Y. Rytz-Froidevaux, R.P. Salathe, H.H. Gilgen: Appl. Phys. A37, 121 (1985)

    Google Scholar 

  7. R.M. Osgood, Jr., H.H. Gilgen: Ann. Rev. Mater. Sci.15, 549–576 (1985)

    Google Scholar 

  8. H.H. Gilgen, C.J. Chen, R.R. Krchnavek, R.M. Osgood, Jr.: InLaser Processing and Diaanostics ed. by D. Bäuerle, Springer Ser. Chem. Phys.39 (Springer, Berlin, Heidelberg 1984) p. 225

    Google Scholar 

  9. H.H. Gilgen: In Proc. of the Material Research Society Annual Meeting in Boston, 1984,Laser Chemical Processing of Semiconductor Devices, ed. by F.A. Houle, T.F. Deutsch, and R.M. Osgood, Jr. (Material Research Society, Pittsburgh, 1984) p. 53

    Google Scholar 

  10. R. Solanki, P.K. Boyer, G.J. Collins: Appl. Phys. Lett.41, 1048 (1982)

    Google Scholar 

  11. T.F. Deutsch, D.D. Rathman: Appl. Phys. Lett.45, 623 (1984)

    Google Scholar 

  12. T.H. Baum, C.R. Jones: Appl. Phys. Lett.47, 538 (1985)

    Google Scholar 

  13. F.A. Houle, C.R. Jones, T. Baum, C. Pico, C. Kovac: Appl. Phys. Lett.46, 204 (1985)

    Google Scholar 

  14. S.A. Allen, A.B. Triggubo, R.Y. Jan: In Proc. of the Material Research Society Annual Meeting in Boston, 1982,Laser Diagnostics and Photochemical Processing for Semiconductor Devices, ed. by R.M. Osgood, Jr., S.R. Brueck, and H.R. Schlossberg (North-Holland, New York 1983) Vol. 17, p. 207

    Google Scholar 

  15. D. Bäuerle (ed.):Laser Processing and Diagnostics, Springer Ser. Chem. Phys.39 (Springer, Berlin, Heidelberg 1984) p. 166

    Google Scholar 

  16. I. Wender, P. Pino:Organic Syntheses via Metal Carbonyls (Interscience, Wiley, New York 1968) p. 1

    Google Scholar 

  17. D. Braichotte, H. Van den Berg: InLaser Processing and Diagnostics, ed. by D. Bäuerle, Springer Ser. Chem. Phys.39 (Springer, Berlin, Heidelberg 1984) p. 183

    Google Scholar 

  18. Q. Mingxin, R. Monot, H. Van den Bergh: Scientia Sinica-A1, 85 (1985)

    Google Scholar 

  19. G.K. White, S.B. Woods: Philos. Trans. R. Soc. (London) A251, 273 (1959)

    Google Scholar 

  20. M. Wrighton: Chem. Rev.74, 401–430 (1974)

    Google Scholar 

  21. C.J. Chen, R.M. Osgood, Jr.: InLaser Diagnostics and Photochemical Processing for Semiconductor Devices, ed. by R. M. Osgood, Jr., S.R. Breuck, and H.R. Schlossberg (North-Holland, New York 1983) Vol. 17, p. 169

    Google Scholar 

  22. T.M. Mayer, G.J. Fisanick, T.S. Eichelberger IV: J. Appl. Phys.53, 8462 (1982)

    Google Scholar 

  23. G.D. Flesch, H.J. Svec: J. Chem. Phys.55, 4310 (1971)

    Google Scholar 

  24. F.A. Cotton, A.K. Fischer, G. Wilkinson: J. Am. Chem. Soc.78, 5168 (1956)

    Google Scholar 

  25. G. Nathanson, B. Gitlin, A.M. Rosan, J.T. Yardley: J. Chem. Phys.74, 361 (1981)

    Google Scholar 

  26. J.T. Yardley, B. Gitlin, G. Nathanson, A.M. Rosan: J. Chem. Phys.74, 378 (1981)

    Google Scholar 

  27. R.L. Whetten, K.J. Fu, E.R. Grant: J. Chem. Phys.79, 4899 (1983)

    Google Scholar 

  28. K.E. Lewis, D.M. Golden, G.P. Smith: J. Am. Chem. Soc.106, 3905–3912 (1984)

    Google Scholar 

  29. F.A. Cotton, A.K. Fischer, G. Wilkinson: J. Am. Chem. Soc.81, 800 (1959)

    Google Scholar 

  30. C.F. Powell, J.H. Oxley, J.M. Blocker, Jr.:Vapor Deposition (Wiley, New York 1966)

    Google Scholar 

  31. L.H. Kaplan, F.M. d'Heuerle: J. Electrochem. Soc.117, 693 (1970)

    Google Scholar 

  32. H.J. Freund, F. Greuter, D.H. Heskett, E.W. Plummer: Phys. Rev. B28, 727 (1983)

    Google Scholar 

  33. M. Lax: J. Appl. Phys.48, 3919 (1977); Appl. Phys. Lett.33, 786 (1978)

    Google Scholar 

  34. K. Piglmayer, J. Doppelbauer, D. Bäuerle: InLaser-Controlled Chemical Processing of Surfaces, ed. by A.W. Johnson, D.J. Ehrlich, and H.R. Schlossberg (North-Holland, New York 1984) Vol. 29, p. 47

    Google Scholar 

  35. Refs. [18, 42, 43] in Y.S. Touloukian, R.W. Powell, C.Y. Ho, P.G. Klemens:Thermal Conductivity of Nonmetallic Solids in Thermophysical Properties of Matter (IFI/Plenum, New York 1970) Vol. 2, p. 922

    Google Scholar 

  36. H.J. Zeiger, J.Y. Tsao, D.J. Ehrlich: In Proc. Topical Meeting on the Microphysics of Surfaces, Beams, and Adsorbates, ed. by D.J. Ehrlich and T.J. Chuang (American Vacuum Society by Am. Inst. of Physics, New York 1985) p. 1436

    Google Scholar 

  37. M. Born, E. Wolf:Principles of Optics (Pergamon, Oxford 1980) p. 627

    Google Scholar 

  38. L.I. Maissel, R. Glang: InHandbook of Thin Film Technology, ed. by L.I. Maissel (McGraw-Hill, New York 1970)

    Google Scholar 

  39. D.J. Ehrlich, R.M. Osgood, Jr., T.F. Deutsch: J. Electrochem. Soc.128, 2041 (1981)

    Google Scholar 

  40. H.E. Carlton, W.M. Goldberger: J. Metals17, 611 (1965)

    Google Scholar 

  41. P. Petroff, T.T. Sheng, A.K. Sinha, G.A. Rozgonyi, F.B. Alexander: J. Appl. Phys.44, 2545 (1973)

    Google Scholar 

  42. R. Wilson, F.A. Houle, C.R. Jones:Laser Chemical Processing of Semiconductor Devices, ed. by F.A. Houle, T.F. Deutsch, and R.M. Osgood, Jr. (Material Research Society, Pittsburgh 1984) p. 90

    Google Scholar 

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Gilgen, H.H., Cacouris, T., Shaw, P.S. et al. Direct writing of metal conductors with near-uv light. Appl. Phys. B 42, 55–66 (1987). https://doi.org/10.1007/BF00694811

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  • DOI: https://doi.org/10.1007/BF00694811

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