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Synthesis and characterization of silicon-containing graft copolymers

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Abstract

Poly(4-t-butoxycarbonyloxystyrene)-g-poly(dimethylsiloxane) and poly(t-butylmethacrylate)-g-poly(dimethylsiloxane) with various chemical compositions were synthesized via free radical polymerization of 4-t-butoxycarbonyloxystyrene (TBCS) or t-butylmethacrylate (TBMA) with silicone macromers. These macromers were prepared by anionic ring-opening polymerization of hexamethylcyclotrisiloxane (D3) and subsequent termination with a chlorosilane compound having a methacrylate functionality. The morphology of the graft copolymer systems was investigated by DSC and TEM.

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Author notes

  1. J. C. van de Grampel

    Present address: Department of Polymer Chemistry, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands

Authors and Affiliations

  1. Department of Polymer Chemistry, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands

    R. Puyenbroek & P. J. Werkman

  2. Centre for Submicron Technology, DIMES, Delft University of Technology, Feldmannweg 17, 2628 CT, Delft, The Netherlands

    B. A. C. Rousseeuw & E. W. J. M. van der Drift

Authors
  1. R. Puyenbroek
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  2. P. J. Werkman
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  3. B. A. C. Rousseeuw
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  4. E. W. J. M. van der Drift
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  5. J. C. van de Grampel
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Puyenbroek, R., Werkman, P.J., Rousseeuw, B.A.C. et al. Synthesis and characterization of silicon-containing graft copolymers. J Inorg Organomet Polym 4, 289–299 (1994). https://doi.org/10.1007/BF00683721

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  • DOI: https://doi.org/10.1007/BF00683721

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