Skip to main content
SpringerLink
Log in

Solvent effects on electron transfer reactions. The system iron(III)-phenothiazine in water-alcohol mixtures

  • Full Papers
  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Summary

The effect of solvent composition (aqueous mixtures of methanol, ethanol, propan-1-ol and propan-2-ol) on the rate constants and activation parameters of the electron transfer between iron(III) and phenothiazine has been investigated. The dependence of the kinetic parameters on the solvent composition is discussed with reference to previously investigated systems.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. W. L. Reynolds and R. W. Lumry:Mechanisms of Electron Transfers, Ronald Press, New York, 1966; E. S. Amis,Solvent Effects on Reaction Rates and Mechanisms, Academic Press, New York, 1966.

    Google Scholar 

  2. R. Schmid:Rev. Inorg. Chem., 1, 117 (1979).

    CAS  Google Scholar 

  3. E. Pelizzetti and R. Giordano:J. Inorg. Nucl. Chem., in press.

  4. K. Ohashi, T. Amano and K. Yamamoto:Inorg. Chem., 16, 3364 (1977).

    Article  CAS  Google Scholar 

  5. M. Kimura and G. Wada:Inorg, Chem., 17, 2239 (1978).

    Article  CAS  Google Scholar 

  6. D. Cohen, J. C. Sullivan, E. S. Amis and J. C. Hindman:J. Am. Chem. Soc., 78, 1543 (1956).

    Article  CAS  Google Scholar 

  7. B. R. Baker, F. Basolo and H. M. Neumann:J. Phys. Chem., 63, 371 (1959).

    Article  CAS  Google Scholar 

  8. T. J. Kemp, P. Moore and G. R. Quick:J. Chem. Soc. Perkin. II, 291 (1980).

    Google Scholar 

  9. E. Pelizzetti and E. Pramauro:Ber. Bunsenges. Phys. Chem., 83, 996 (1979).

    Article  CAS  Google Scholar 

  10. E. Pelizzetti and E. Mentasti:Inorg. Chem., 18, 583 (1979).

    Article  CAS  Google Scholar 

  11. J. R. Brandon and L. M. Dorfman:J. Chem. Phys., 53, 3849 (1970); R. W. Callahan, F. R. Keene, T. J. Meyer and D. J. Salmon:J. Am. Chem. Soc., 99, 1064 (1977).

    Article  CAS  Google Scholar 

  12. O. I. Micic and B. Cercek:J. Phys. Chem., 78, 285 (1974).

    Article  CAS  Google Scholar 

  13. N. Tanaka:Electrochim. Acta, 21, 701 (1976).

    Article  CAS  Google Scholar 

  14. W. Jaenicke and P. H. Schweitzer:Z. phys. Chem. N. F., 52, 104 (1967).

    Article  CAS  Google Scholar 

  15. F. Franks and J. G. Ives,Quart. Rev. Chem. Soc., 20, 1 (1966).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Istituto di Chimica Analitica, Università di Torino, Via Giuria 5, 10125, Torino, Italy

    Ezio Pelizzetti & Edmondo Pramauro

Authors
  1. Ezio Pelizzetti
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Edmondo Pramauro
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pelizzetti, E., Pramauro, E. Solvent effects on electron transfer reactions. The system iron(III)-phenothiazine in water-alcohol mixtures. Transition Met Chem 6, 334–336 (1981). https://doi.org/10.1007/BF00623649

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00623649

Keywords

Search

Navigation