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Heterocyclic analogs of pleiadiene. 49. Mass spectra of some N-substituted perimidines and 2,3-dihydroperimidines

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The mass spectra of nine compounds of the perimidine series, as well as 1,3-dimethyl derivatives of 2,3-dihydroperimidine, perimidone, and thioperimidone, were obtained and are discussed. The perimidines are distinguished by their high resistance to electron impact. The initial fragmentation of their molecular ions is characterized by detachment of the substituent attached to nitrogen, as well as by detachment of a hydrogen atom from the N-methyl group. It is proposed that the intensities of the doubly charged M2+ ions be used to estimate the π-donor properties of heterocyclic compounds.

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Authors and Affiliations

  1. Rostov State University, 344006, Rostov-on-Don

    N. A. Klyuev, A. F. Pozharskii, A. B. Belikov & V. M. Adanin

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  1. N. A. Klyuev
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  2. A. F. Pozharskii
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  3. A. B. Belikov
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  4. V. M. Adanin
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Additional information

See [1] for communication 48.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 684–690, May, 1980.

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Klyuev, N.A., Pozharskii, A.F., Belikov, A.B. et al. Heterocyclic analogs of pleiadiene. 49. Mass spectra of some N-substituted perimidines and 2,3-dihydroperimidines. Chem Heterocycl Compd 16, 535–540 (1980). https://doi.org/10.1007/BF00561356

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  • DOI: https://doi.org/10.1007/BF00561356

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