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Improvement of chemical durability of high expansion glasses by ion exchange

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Abstract

In order to prepare a high expansion glass with good chemical durability, Na2O · 2SiO2 glass was ion-exchanged in molten LiNO3 at 460 to 520° C. A Li2O rich layer, of 100 to 200 μm thickness, was produced on the glass surface. Corrosion rate in hot water (98° C) and thermal expansion coefficient were measured. The thin layer on the surface had a much lower corrosion rate in hot water and a lower expansion coefficient than the bulk glass. Because the ion-exchanged layer was thin with respect to the bulk glass, an overall high expansion was maintained. However, it acted as a protective layer giving rise to improved chemical durability.

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References

  1. W. D. Kingery, “Introduction to Ceramics” (John Wiley and Sons, New York, 1976).

    Google Scholar 

  2. “Polymer Handbook”, edited by J. Brandrup and E. H. Immergut (John Wiley and Sons, New York, 1966).

    Google Scholar 

  3. “Encyclopedia of Polymer Science and Technology”, Vols. 10 and 13, edited by N. M. Bikales (John Wiley and Sons, New York, 1970).

    Google Scholar 

  4. G. W. Morey, “The Property of Glass” (Reinhold Publishing Corporation, New York, 1954) Chap. 4 and 11.

    Google Scholar 

  5. W. A. Weyl and E. C. Marboe, “The Constitution of Glasses”, Vol. II, Part 2 (Wiley, New York, 1967) p. 1086.

    Google Scholar 

  6. T. Minami and J. D. Mackenzie, J. Amer. Ceram. Soc. 60 (1971) 232.

    Google Scholar 

  7. E. L. Mochel, ibid 49 (1966) 585.

    Google Scholar 

  8. H. M. Garfinkel, D. L. Rothermel and S. D. Stookey, “Advances in Glass Technology” (Plenum Press, New York, 1962) p. 404.

    Google Scholar 

  9. H. P. Hood and S. D. Stookey, US Patent, 2779136 (1957).

  10. R. H. Doremus, “Glass Science” (Wiley, New York, 1973).

    Google Scholar 

  11. M. E. Nordberg, E. L. Mochel, H. M. Garfinkel and J. S. Olcott, J. Amer. Ceram. Soc. 47 (1964) 215.

    Google Scholar 

  12. S. S. Kistler, ibid 45 (1962) 59.

    Google Scholar 

  13. G. H. Frischat, “Ionic Diffusion in Oxide Glasses” (Trans. Tech. Publications, Ohio, 1975).

    Google Scholar 

  14. R. Terai and R. Hayami, J. Non-Cryst. Solids 18 (1975) 217.

    Google Scholar 

  15. H. Schaefer and H. Maywald, Glastechn. Ber. 40 (1967) 253.

    Google Scholar 

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Author notes

  1. Kazumasa Matusita

    Present address: Department of Industrial Chemistry, Mie University, Tsu, 514, Mie, Japan

Authors and Affiliations

  1. Materials Department, School of Engineering and Applied Science, University of California, 90024, Los Angeles, California, USA

    Kazumasa Matusita & John D. Mackenzie

Authors
  1. Kazumasa Matusita
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  2. John D. Mackenzie
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Matusita, K., Mackenzie, J.D. Improvement of chemical durability of high expansion glasses by ion exchange. J Mater Sci 13, 1026–1030 (1978). https://doi.org/10.1007/BF00544697

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  • DOI: https://doi.org/10.1007/BF00544697

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