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Formation of bicyclic compounds in the reaction of 3-methyl-2,3-epoxysulfolane with thiocyanic acid

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

In the presence of an equivalent amount of sulfuric acid 3-methyl-2,3-epoxysulfolane reacts with sodium thiocyanate with primary opening of the oxy ring at the C(3)-O bond to give, as the principal product, 5-methyl-3-oxo-2-oxa-4,8-dithiabicyclo[3.3.0]octane 8,8-dioxide.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, 420083, Kazan

    L. A. Mukhamedova, L. I. Kursheva, K. M. Enikeev & A. V. Il'yasov

Authors
  1. L. A. Mukhamedova
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  2. L. I. Kursheva
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  3. K. M. Enikeev
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  4. A. V. Il'yasov
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 331–335, March, 1985.

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Mukhamedova, L.A., Kursheva, L.I., Enikeev, K.M. et al. Formation of bicyclic compounds in the reaction of 3-methyl-2,3-epoxysulfolane with thiocyanic acid. Chem Heterocycl Compd 21, 273–276 (1985). https://doi.org/10.1007/BF00506663

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  • DOI: https://doi.org/10.1007/BF00506663

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