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Investigation of the stereochemical direction of the cyanoethylation of six-membered heterocyclic ketones as a function of the nature of the heteroatom

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Only a mono (cyanoethyl) compound is formed from thiopyranone in the cyanoethylation of six-membered heterocyclic ketones that contain a methyl group attached to the C2 atom of the heteroring, whereas primarily bis- and tris(cyanoethyl) derivatives are obtained from pyranone due to the effect of the heteroatom.

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Literature cited

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Authors and Affiliations

  1. Institute of the Chemistry of Petroleum and Natural Salts, Academy of Sciences of the Kazakh SSR, 465050, Gurev

    K. Kh. Tokmurzin, V. V. Kozyrev & A. Sh. Sharifkanov

Authors
  1. K. Kh. Tokmurzin
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  2. V. V. Kozyrev
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  3. A. Sh. Sharifkanov
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1342–1343, October, 1982.

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Tokmurzin, K.K., Kozyrev, V.V. & Sharifkanov, A.S. Investigation of the stereochemical direction of the cyanoethylation of six-membered heterocyclic ketones as a function of the nature of the heteroatom. Chem Heterocycl Compd 18, 1036–1038 (1982). https://doi.org/10.1007/BF00503187

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  • DOI: https://doi.org/10.1007/BF00503187

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