Abstract
N-substituted derivatives of perimidine and aceperimidine are readily aminated by sodium amide in position 2 with the formation of previously unknown 2-amino derivatives. Some other reactions taking place at the μ-carbon atom of perimidine have also been studied: direct hydroxylation with caustic potash, the ammonolysis of the 2-chloro derivatives, the action of alkalis on the quarternary salts, and the direct thiolation of the perimidines with sulfur, leading to 2-mercaptoperimidines.
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For Communication III, see [1].
Translated from Khimiya Geterotsiklicheskikh Soedinenii, Vol. 6, No. 8, pp. 1129–1132, August, 1970.
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Pozharskii, A.F., Kashparov, I.S. Heterocyclic analogs of pleiadiene. Chem Heterocycl Compd 6, 1055–1058 (1970). https://doi.org/10.1007/BF00480649
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DOI: https://doi.org/10.1007/BF00480649