Skip to main content
SpringerLink
Log in

Investigation of 2,6-diarylthiacyclohexanes and their complexes with Pt(II) and Pd(II) by 1H and 13C NMR spectroscopy

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A conclusion regarding a diequatorial orientation of the aryl substituents was drawn on the basis of a study of the 1H and 13C NMR spectra of 2,6-diarylthiacyclohexanes. A trans structure of the complexes with an equatorial S→metal bond was established by a comparative analysis of the 13C NMR spectra of 2,6-diarylthiacyclohexanes and their complexes with Pt(II) and Pd(II).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature Cited

  1. V. G. Kharchenko, O. A. Bozhenova, and A. D. Shebaldova, Zh. Org. Khim., 18, 2435 (1982).

    Google Scholar 

  2. O. A. Bozhenova, V. G. Kharchenko, and A. D. Shebaldova, Koordinats. Khim., 9, 1096 (1983).

    Google Scholar 

  3. V. G. Kharchenko and N. I. Kozhevnikova, Research on the Synthesis and Catalysis of Organic Compounds [in Russian], Izd. Saratovsk. Gosudarstv. Univ., Saratov (1983), p. 19.

    Google Scholar 

  4. V. G. Kharchenko, N. I. Kozhevnikova, A. A. Shcherbakov, G. G. Aleksandrov, and Yu. T. Struchkov, Khim. Geterotsikl. Soedin., No. 3, 324 (1980).

    Google Scholar 

  5. N. M. Sergeev and O. A. Subbotin, Usp. Khim., 47, 477 (1978).

    Google Scholar 

  6. N. M. Krapivin and M. I. Perepelitchenko, Izv. Akad. Nauk SSSR, Ser. Khim., No. 2, 452 (1982).

    Google Scholar 

  7. F. W. Wehrlin and T. Wirthlin, Interpretation of Carbon-13 NMR Spectra, Heyden, London (1978), p. 310.

    Google Scholar 

  8. R. K. Freidlina, V. I. Dostovalova, N. A. Kuzimina, and E. S. Chukovskaya, Org. Magn. Reson., 15, 133 (1981).

    Google Scholar 

  9. R. L. Willer and E. L. Eliel, J. Am. Chem. Soc., 99, 1925 (1977).

    Google Scholar 

  10. D. K. Dallin and D. M. Grant, J. Am. Chem. Soc., 94, 5318 (1972).

    Google Scholar 

  11. E. L. Eliel, W. F. Bailey, L. D. Kopp, R. L. Willer, D. M. Grant, R. Bertrant, K. A. Christensen, D. K. Dallin, M. W. Duch, E. Wenkert, F. M. Schell, and D. W. Cochran, J. Am. Chem. Soc., 97, 322 (1975).

    Google Scholar 

  12. N. M. Sergeev, NMR Spectroscopy [in Russian], Izd. Moskovsk. Gosudarstv. Univ., Moscow (1981).

    Google Scholar 

  13. R. P. Rooney and S. A. Evans, J. Org. Chem., 45, 180 (1980).

    Google Scholar 

  14. S. G. Murray and F. R. Hurtley, Chem. Rev., 81, 365 (1981).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. G. Chernyshevskii Saratov State University, 410601, Saratov

    V. G. Kharchenko, A. D. Shebaldova, O. A. Bozhenova & N. N. Sorokin

Authors
  1. V. G. Kharchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. D. Shebaldova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. A. Bozhenova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. N. Sorokin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 609–613, May, 1987.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kharchenko, V.G., Shebaldova, A.D., Bozhenova, O.A. et al. Investigation of 2,6-diarylthiacyclohexanes and their complexes with Pt(II) and Pd(II) by 1H and 13C NMR spectroscopy. Chem Heterocycl Compd 23, 502–506 (1987). https://doi.org/10.1007/BF00476375

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00476375

Keywords

Search

Navigation