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Chemistry of Heterocyclic Compounds

, Volume 9, Issue 1, pp 22–25 | Cite as

Synthesis and some transformations of pyrroles with aliphatic acyl substituents

  • A. F. Mironov
  • N. B. Ol'shanskaya
  • V. P. Zhestkov
  • R. P. Evstigneeva
Article
  • 34 Downloads

Abstract

A number of higher aliphatic pyrryl ketones were synthesized. It is shown that a carbethoxy group in the 5 position of the pyrrole ring relatively weakly deactivates the 3 position of the ring to electrophilic attack during Friedel—Crafts acylation but hinders this reaction considerably when it is in the adjacent 4 position. The oxidation of the α-methyl group in a series of pyrryl ketones and the corresponding alcohols was studied.

Keywords

Oxidation Alcohol Organic Chemistry Ketone Pyrrole 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Consultants Bureau, a division of Plenum Publishing Corporation 1975

Authors and Affiliations

  • A. F. Mironov
    • 1
  • N. B. Ol'shanskaya
    • 1
  • V. P. Zhestkov
    • 1
  • R. P. Evstigneeva
    • 1
  1. 1.M. V. Lomonosov Moscow Institute of Precision Chemical EngineeringUSSR

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