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Organosilicon compounds of the furan series

X. Hydrosilylation of 2-vinylfuran

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

2-Vinylfuran is hydrosilylated by trichlorosilane, alkyldichlorosilanes, triethoxysilane, alkyldialkoxysilanes, trialkylsilanes, and tetraethyldisoloxane, in the presence of H2PtCl6 · 6H2O, 1% Pt/C, and 1% Pd/C. The structures of the products are shown by PMR, and IR spectra, and proved by reverse synthesis. It is shown that in the majority of cases hydrosilylation is in accordance with Farmer's rule. New views on the mechanism of hydrosilylation are put forward.

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References

  1. E. Ya. Lukevits and M. G. Voronkov, KhGS, 463, 1965.

  2. E. Ya. Lukevits and M. G. Voronkov, KhGS, 179, 1965.

  3. E. Ya. Lukevits and M. G. Voronkov, Hydrosilylation, Hydrogermylation, and Hydrostannylation [in Russian], Izd-vo AN Latv. SSR, Riga, 18, 1964.

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Authors and Affiliations

  1. Institute of Organic Synthesis AS Latvian SSR, Riga

    E. Ya. Lukevits & M. G. Voronkov

Authors
  1. E. Ya. Lukevits
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  2. M. G. Voronkov
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Additional information

For Part IX see [1].

Thanks are due to A. Grinvald and O. Neiland for the IR spectra, and to R. Gavar for the EPR work.

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Lukevits, E.Y., Voronkov, M.G. Organosilicon compounds of the furan series. Chem Heterocycl Compd 1, 325–331 (1966). https://doi.org/10.1007/BF00473801

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  • DOI: https://doi.org/10.1007/BF00473801

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