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Stable tetragonal HTSC Fe-doped 1-2-3 phase with oxygen excess

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Abstract

Mössbauer study was performed on the YBa2Cu2.95Fe0.05O y compound prepared in three different states: orthorhombic phase with y℞7, tetragonal non-superconducting phase with oxygen deficiency, and a new tretragonal superconducting phase with oxygen excess (y>7). The new synthesis method was used for preparation of the Fe-doped YBa2Cu3O y (named 1-2-3) compound. The comparison of Mössbauer spectra of three different states allowed us to identify the oxygen environments of the Fe atoms in the Cu1 positions.

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Sedykh, V., Strukova, G.K., Zverkova, I.I. et al. Stable tetragonal HTSC Fe-doped 1-2-3 phase with oxygen excess. Appl. Phys. A 54, 497–499 (1992). https://doi.org/10.1007/BF00324327

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  • DOI: https://doi.org/10.1007/BF00324327

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