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Application of photosensitive surfactant based on natural rubber in emulsion polymerizations

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Summary

Photosensitive surfactant was prepared by incorporation of maleic anhydride to natural rubber, followed by introduction of cinnamate groups and neutralization of the remaining carboxylic groups. The surfactant was used in emulsion polymerization of styrene and acrylic monomers, giving rise to stable reactive emulsion. Coated onto HDPE, this emulsion lead to solid films which were submitted to UV irradiation.

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Authors and Affiliations

  1. Instituto de Macromoléculas Professora Eloisa Mano, Universidade Federal do Rio de Janeiro, P.O. Box 68 525, 21945-970, Rio de Janeiro, RJ, Brazil

    Helcio O. Rocha, Cristina T. Andrade & Leila L. Y. Visconte

  2. Tokyo Daiichi Gakashu Center, The University of the Air, 4-1-1 Shimouma, Setagayaku, 154, Tokyo, Japan

    Chiaki Azuma

Authors
  1. Helcio O. Rocha
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  2. Cristina T. Andrade
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  3. Chiaki Azuma
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  4. Leila L. Y. Visconte
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Rocha, H.O., Andrade, C.T., Azuma, C. et al. Application of photosensitive surfactant based on natural rubber in emulsion polymerizations. Polymer Bulletin 36, 197–202 (1996). https://doi.org/10.1007/BF00294906

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  • DOI: https://doi.org/10.1007/BF00294906

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