Summary
Resins with adsorption properties for copper(II) and uranium(VI) were synthesized by crosslinking of linear polyethyleneimine and subsequent N-alkylation with dimethyl sulphate. The crosslinking agents used are: 1,9-dibromononane and 1,10-dibromodecane. The influence of the pH on the retention, maximum capacity of load and elution were studied. The morphology of the resins has been examined by scanning electron microscopy and their thermal stability by TGA.
Similar content being viewed by others
References
T.Tsuchida and N.Nishida, Adv.Polym.Sci. 24, 2 (1977).
M.Kaneko and T.Tsuchida, J.Macromol.Sci.Rev. 16, 397 (1981).
K.Geckeler, H.Weingartner and E.Bayer, Pure Appl.Chem. 52, 1883(1980)
A.A.Efendiev and V.A.Kabanov, Pure ApplChem. 54, 2077 (1981).
E.J.Shepherd and A.Kitchener, J.Chem.Soc. 86 (1957).
S.Nonogaki, S.Makishima and Y.Yoneda, J.Phys.Chem. 62, 601 (1958).
J.J.Anzi, I.Sakata, Y.Susuki, A.Ueno and T.Osa, J.Polym.Sci.Polym. Chem. Ed. 21, 855 (1983).
T.Saegusa, S.Kobayashi and Y.Yoneda, J.Appl.Polym.Sci., 21, 2489(1977).
J.Bartulín, H.A.Maturana, B.L.Rivas and M.Rodríguez, An.Quim 76, 221 (1982).
J.Bartulín, H.A.Maturana, B.L.Rivas and M.Rodríguez, An.Quim. 76, 224 (1982).
B.L.Rivas, H.A.Maturana, I.Perich and U.Angne, Polym.Bull. 15, 121 (1986).
B.L.Rivas, H.A.Maturana, I.Perich and U.Angne, Polym.Bull. 14, 239 (1985).
B.L.Rivas and J.Bartulín, Bol.Soc.Chil.Quim. 31, 37 (1986).
J.Bartulín, B.L.Rivas, M.Rodríguez and U.Angne, Makromol.Chem. 183, 2935 (1982).
J.A.Pérez-Bustamante and F.Palomares Delgado, Analyst, 96, 407 (1971).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Rivas, B.L., Maturana, H.A., Angne, U. et al. Resins with retention properties for heavy metals. Part 4. Polymer Bulletin 16, 305–309 (1986). https://doi.org/10.1007/BF00255001
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00255001