Abstract
Mercury adsorbed from HgCl2 and 2-methoxy-ethylmercury chloride (Aretan) solutions by three contrasting soils showed a dependence on soil: solution ratio and initial Hg concentration in soil solution. Changing the soil solution ratio from 1: 10 to 1 : 100 but keeping the initial concentration constant resulted in an increase in Hg adsorption from both Hg compounds. A similar change in soil: solution ratio accompanied by a decrease in initial concentration, on the other hand, resulted in decrease in Hg adsorption. Upon manipulating of the pH of the surface soils, adsorption of HgCl2 at 100 mg Hg L−1 concentration increased from about 701 :o over 95 mg Hg kg−1 when pH was raised from 5.0 to 8.0. Precipitation of Hg may also have contributed to this trend. Aretan adsorption by these soils, on the other hand, changed little with change in pH. Removal of organic matter from soil resulted in large reductions of Hg adsorbed, as much as 95 % from the HgCl2 solutions, but only up to 31 % from Aretan solutions. This suggests that organic matter in soil played a mayor role in the adsorption of inorganic Hg whereas the soils' mineral fractions were involved more in the adsorption of the organic Hg compound.
Similar content being viewed by others
References
Anderson, B. J. and Jenne, E. A.: 1970, Soil Sci. 109, 163.
Andren, A. W. and Harriss, R. C.: 1975, Geochim. Cosmochim. Acta 39, 1253.
Aomine, S. and Inoue, K.: 1967, Soil Sci. Plant Nutr. (Tokyo) 13, 195.
Cotton, F. A. and Wilkinson, G.: 1966, Advanced Inorganic Chemistry, 2nd ed., Wiley Interscience, New York, p. 615.
Estes, G. O., Knoop, W. E., and Houghton, F. D.: 1973, J. Environ. Qual. 2, 451.
Fang, S. C.: 1978, Environ. Sci. Technol. 12, 285.
Farrah, H. and Pickering, W. F.: 1978, Water, Air, and Soil Pollut. 9, 23.
Feick, G., Horne, R. A., and Yeaple, D.: 1972, Science 175, 1142.
Forbes, E. A., Posner, A. M., and Quirk, J. P.: 1974, J. Colloid Interface Sci. 49, 403.
Gotoh, S., Tokudome, S., and Koga, H.: 1978, Soil Sci. Plant Nutr. (Tokyo) 24, 391.
Hahne, H. C. H. and Kroontje, W.: 1973a, Soil Sci. Soc. Amer. Proc. 37, 838.
Hahne, H. C. H. and Kroontje, B.: 1973b, J. Environ. Qual. 2, 444.
Harsh, J. B. and Doner, H. E.: 1981, J. Environ. Qual. 10, 333.
Helling, C. S., Chesters, G., and Gorey, R. B.: 1964, Soil Sci. Soc. Amer. Proc. 28, 517.
Hogg, T. J., Bettany, J. R., and Stewart, J. W. B.: 1978, J. Environ. Qual. 7, 440.
Inoue, K. and Aomine, S.: 1969, Soil Sci. Plant Nutr. (Tokyo) 15, 86.
Jenne, E. A.: 1970, ‘Atmospheric and Fluvial Transport of Mercury’, in Geol. Surv. Prof. Pap.713, Mercury in the Environment. U.S. Govt. Printing Office, Washington, D.C., pp. 40–45.
Khalid, R. A., Gambrell, R. P., and Patrick Jr., W. H.: 1977, ‘Sorption and Release of Mercury by Mississippi River Sediment as Affected by pH and Redox Potential’, in H. Drucker and R. E. Wildung (eds.), Biological Implications of Metals in the Environment, Proceedings of the 15th Annual Hanford Life Science Symposium, Richland, Washington. September 29–October 1, 1975, pp. 297–314.
Krauskopf, K. B.: 1956, Geochim. Cosmochim. Acta 9, 1.
Kunze, G. W.: 1965, ‘Pretreatment for Mineralogical Analysis’, in C. A. Black (ed.), Methods of Soil Analysis, Part I, Physical and Mineralogical Properties, Including Statistics of Measurement and Sampling, American Society of Agronomy, Madison, pp. 568–577.
Låg, J. and Steinnes, E.: 1978. Acta Agric. Scand. 28, 393.
Lamar, W. L.: 1968, ‘Evaluations of Organic Colour and Iron in Natural Surface Waters’, In: Geol. Surv. Prof. Pap. 600-D, U.S. Govt. Printing Office, Washington, D.C., pp. D24-D29.
Landa, E. R.: 1978, Geochim. Cosmochim. Acta 42, 1407.
Lockwood, R. A. and Chen, K. Y.: 1973, Environ. Sci. Technol. 7, 1028.
Newton, D. W., Ellis Jr., R., and Paulsen, G. M.: 1976, J. Environ. Qual. 5, 251.
Reimers, R. S. and Krenkel, P. A.: 1974, J. Water Pollut. Control Fed. 46, 352.
Semu, E., Singh, B. R., and Selmer-Olsen, A. R.: 1987, Water, Air, and Soil Pollut. 32, 11 (this volume).
Trost, P. B. and Bisque, R. E.: 1972, ‘Distribution of Mercury in Residual Soils’, in: R. Hartung and B. D. Dinman (eds.), Environmental Mercury contamination, Ann Arbor Science Publishers, Ann Arbor, Mich., pp. 178–196.
Waksman, S. A.: 1938, Humus: Origin, Chemical Composition andImportance in Nature, Williams and Wilkins Co., Baltimore.
Author information
Authors and Affiliations
Additional information
Author for all correspondence.
Rights and permissions
About this article
Cite this article
Semu, E., Singh, B.R. & Selmer-Olsen, A.R. Adsorption of mercury compounds by tropical soils II. Effect of soil: Solution ratio, ionic strength, pH, and organic matter. Water Air Soil Pollut 32, 1–10 (1987). https://doi.org/10.1007/BF00227678
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00227678