Abstract
A numerical method is proposed to model Kelvin probe force microscopy of hetero-structures in the dark and under illumination. It is applied to FTO/TiO2 and FTO/TiO2/MAPbI3 structures. The presence of surface states on the top of the TiO2 layers are revealed by combining theoretical computation and experimental results. Basic features of Kelvin probe force microscopy under illumination, namely surface photovoltage, are simulated as well. The method paves the way toward further investigations of more complicated optoelectronic devices.
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Aharon, S., Gamliel, S., Cohen, B.E., Etgar, L.: Depletion region effect of highly efficient hole conductor free CH3NH3PbI3 perovskite solar cells. Phys. Chem. Chem. Phys. 16, 10512–10518 (2014). https://doi.org/10.1039/c4cp00460d
Ball, J.M., Stranks, S.D., Hörantner, M.T., Hüttner, S., Zhang, W., Crossland, E.J.W., Ramirez, I., Riede, M., Johnston, M.B., Friend, R.H., Snaith, H.J.: Optical properties and limiting photocurrent of thin-film perovskite solar cells. Energy Environ. Sci. 8, 602–609 (2015). https://doi.org/10.1039/C4EE03224A
Barnea-Nehoshtan, L., Kirmayer, S., Edri, E., Hodes, G., Cahen, D.: Surface photovoltage spectroscopy study of organo-lead perovskite solar cells. J. Phys. Chem. Lett. 5, 2408–2413 (2014). https://doi.org/10.1021/jz501163r
Bergmann, V.W., Guo, Y., Tanaka, H., Hermes, I.M., Li, D., Klasen, A., Bretschneider, S.A., Nakamura, E., Berger, R., Weber, S.A.L.: Local time-dependent charging in a perovskite solar cell. ACS Appl. Mater. Interfaces. 8, 19402–19409 (2016). https://doi.org/10.1021/acsami.6b04104
Brattain, W.H., Bardeen, J.: Surface properties of germanium. Bell Syst. Tech. J. 32, 1–41 (1953). https://doi.org/10.1002/j.1538-7305.1953.tb01420.x
Challinger, S.E., Baikie, I.D., Harwell, J.R., Turnbull, G.A., Samuel, I.D.W.: An investigation of the energy levels within a common perovskite solar cell device and a comparison of DC/AC surface photovoltage spectroscopy Kelvin probe measurements of different MAPBI3 perovskite solar cell device structures. MRS Adv (2017). https://doi.org/10.1557/adv.2017.72
Chen, Y.-J., Zhang, M.-J., Yuan, S., Qiu, Y., Wang, X.-B., Jiang, X., Gao, Z., Lin, Y., Pan, F.: Insight into interfaces and junction of polycrystalline silicon solar cells by kelvin probe force microscopy. Nano Energy 36, 303–312 (2017). https://doi.org/10.1016/j.nanoen.2017.04.045
Colella, S., Mosconi, E., Fedeli, P., Listorti, A., Gazza, F., Orlandi, F., Ferro, P., Besagni, T., Rizzo, A., Calestani, G., Gigli, G., De Angelis, F., Mosca, R.: MAPbI3-xClx mixed halide perovskite for hybrid solar cells: the role of chloride as dopant on the transport and structural properties. Chem. Mater. 25, 4613–4618 (2013). https://doi.org/10.1021/cm402919x
Dymshits, A., Henning, A., Segev, G., Rosenwaks, Y., Etgar, L.: The electronic structure of metal oxide/organo metal halide perovskite junctions in perovskite based solar cells. Sci. Rep. 5, 8704 (2015). https://doi.org/10.1038/srep08704
Forro, L., Chauvet, O., Emin, D., Zuppiroli, L., Berger, H., Lévy, F.: High mobility n-type charge carriers in large single crystals of anatase (TiO2). J. Appl. Phys. 75, 633–635 (1994). https://doi.org/10.1063/1.355801
Garrett, J.L., Tennyson, E.M., Hu, M., Huang, J., Munday, J.N., Leite, M.S.: Real-time nanoscale open-circuit voltage dynamics of perovskite solar cells. Nano Lett. (2017). https://doi.org/10.1021/acs.nanolett.7b00289
Gheno, A., Thu Pham, T.T., Di Bin, C., Bouclé, J., Ratier, B., Vedraine, S.: Printable WO3 electron transporting layer for perovskite solar cells: influence on device performance and stability. Sol. Energy Mater. Sol. Cells 161, 347–354 (2017). https://doi.org/10.1016/j.solmat.2016.10.002
González, Y., Abelenda, A., Sánchez, M.: Surface photovoltage spectroscopy characterization of AlGaAs/GaAs laser structures. J. Phys: Conf. Ser. 792, 012021 (2017). https://doi.org/10.1088/1742-6596/792/1/012021
Harwell, J.R., Baikie, T.K., Baikie, I.D., Payne, J.L., Ni, C., Irvine, J.T.S., Turnbull, G.A., Samuel, I.D.W.: Probing the energy levels of perovskite solar cells via Kelvin probe and UV ambient pressure photoemission spectroscopy. Phys. Chem. Chem. Phys. 18, 19738–19745 (2016). https://doi.org/10.1039/C6CP02446G
Huang, Y., Aharon, S., Rolland, A., Pedesseau, L., Durand, O., Etgar, L., Even, J.: Influence of Schottky contact on the C–V and J–V characteristics of HTM-free perovskite solar cells. EPJ Photovolt. 8, 85501 (2017). https://doi.org/10.1051/epjpv/2017001
Jiang, C.-S., Yang, M., Zhou, Y., To, B., Nanayakkara, S.U., Luther, J.M., Zhou, W., Berry, J.J., van de Lagemaat, J., Padture, N.P., Zhu, K., Al-Jassim, M.M.: Carrier separation and transport in perovskite solar cells studied by nanometre-scale profiling of electrical potential. Nat. Commun. 6, 8397 (2015). https://doi.org/10.1038/ncomms9397
Kitaura, M., Azuma, J., Ishizaki, M., Kamada, K., Kurosawa, S., Watanabe, S., Ohnishi, A., Hara, K.: Energy location of Ce3+ 4f level and majority carrier type in Gd3Al2Ga3O12: Ce crystals studied by surface photovoltage spectroscopy. Appl. Phys. Lett. 110, 251101 (2017). https://doi.org/10.1063/1.4987141
Kronik, L.: Surface photovoltage phenomena: theory, experiment, and applications. Surf. Sci. Rep. 37, 1–206 (1999). https://doi.org/10.1016/S0167-5729(99)00002-3
Kronik, L., Shapira, Y.: Surface photovoltage spectroscopy of semiconductor structures: at the crossroads of physics, chemistry and electrical engineering. Surf. Interface Anal. 31, 954–965 (2001). https://doi.org/10.1002/sia.1132
Levine, I., Gupta, S., Brenner, T.M., Azulay, D., Millo, O., Hodes, G., Cahen, D., Balberg, I.: Mobility-lifetime products in MAPbI3 films. J. Phys. Chem. Lett. 7, 5219–5226 (2016). https://doi.org/10.1021/acs.jpclett.6b02287
Lin, Q., Armin, A., Nagiri, R.C.R., Burn, P.L., Meredith, P.: Electro-optics of perovskite solar cells. Nat. Photonics 9, 106–112 (2014). https://doi.org/10.1038/nphoton.2014.284
Minj, A., Skuridina, D., Cavalcoli, D., Cros, A., Vogt, P., Kneissl, M., Giesen, C., Heuken, M.: Surface properties of AlInGaN/GaN heterostructure. Mater. Sci. Semicond. Process. 55, 26–31 (2016). https://doi.org/10.1016/j.mssp.2016.04.005
Miyagi, T., Ogawa, T., Kamei, M., Wada, Y., Mitsuhashi, T., Yamazaki, A., Ohta, E., Sato, T.: Deep level transient spectroscopy analysis of an anatase epitaxial film grown by metal organic chemical vapor deposition. Jpn. J. Appl. Phys. 40, L404–L406 (2001). https://doi.org/10.1143/JJAP.40.L404
Ono, L.K., Qi, Y.: Surface and interface aspects of organometal halide perovskite materials and solar cells. J. Phys. Chem. Lett. 7, 4764–4794 (2016). https://doi.org/10.1021/acs.jpclett.6b01951
Palermo, V., Palma, M., Tomović, Ž., Watson, M.D., Friedlein, R., Müllen, K., Samorì, P.: Influence of molecular order on the local work function of nanographene architectures: a Kelvin-probe force microscopy study. ChemPhysChem 6, 2371–2375 (2005). https://doi.org/10.1002/cphc.200500181
Rosenwaks, P.Y., Saraf, S., Tal, O., Schwarzman, A., Glatzel, D.T., Lux-Steiner, P.D.M.C.: Kelvin probe force microscopy of semiconductors. In: Kalinin, S., Gruverman, A. (eds.) Scanning Probe Microscopy, pp. 663–689. Springer, New York (2007)
Rühle, S., Cahen, D.: Electron tunneling at the TiO2/substrate interface can determine dye-sensitized solar cell performance. J. Phys. Chem. B 108, 17946–17951 (2004). https://doi.org/10.1021/jp047686s
Sadewasser, S., Glatzel, T.: Kelvin Probe Force Microscopy: Measuring and Compensating Electrostatic Forces. Springer Series in Surface Sciences, 2012 edition. Springer (2011)
Silvaco Inc.: ATLAS user’s manual (2012). http://silvaco.com
Singh, S.D., Porwal, S., Sinha, A.K., Ganguli, T.: Surface photovoltage spectroscopy of an epitaxial ZnO/GaP heterojunction. Semicond. Sci. Technol. 32, 055005 (2017). https://doi.org/10.1088/1361-6641/aa6424
Snaith, H.J., Grätzel, M.: The role of a “Schottky Barrier” at an electron-collection electrode in solid-state dye-sensitized solar cells. Adv. Mater. 18, 1910–1914 (2006). https://doi.org/10.1002/adma.200502256
Tang, H., Prasad, K., Sanjinès, R., Schmid, P.E., Lévy, F.: Electrical and optical properties of TiO2 anatase thin films. J. Appl. Phys. 75, 2042–2047 (1994). https://doi.org/10.1063/1.356306
Tsai, H., Nie, W., Lin, Y.-H., Blancon, J.C., Tretiak, S., Even, J., Gupta, G., Ajayan, P.M., Mohite, A.D.: Effect of precursor solution aging on the crystallinity and photovoltaic performance of perovskite solar cells. Adv. Energy Mater. 7, 1602159 (2017). https://doi.org/10.1002/aenm.201602159
Yang, Y., Yan, Y., Yang, M., Choi, S., Zhu, K., Luther, J.M., Beard, M.C.: Low surface recombination velocity in solution-grown CH3NH3PbBr3 perovskite single crystal. Nat. Commun. 6, 7961 (2015). https://doi.org/10.1038/ncomms8961
Zhou, H., Chen, Q., Li, G., Luo, S., Song, T., Duan, H.-S., Hong, Z., You, J., Liu, Y., Yang, Y.: Interface engineering of highly efficient perovskite solar cells. Science 345, 542–546 (2014). https://doi.org/10.1126/science.1254050
Acknowledgements
The work at FOTON was supported by French ANR SupersansPlomb project. Y.H.’s work at Xlim and IPVF was supported by HPERO GDR (CNRS).
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This article is part of the Topical Collection on Numerical Simulation of Optoelectronic Devices, NUSOD’ 17.
Guest edited by Matthias Auf der Maur, Weida Hu, Slawomir Sujecki, Yuh-Renn Wu, Niels Gregersen, Paolo Bardella.
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Huang, Y., Gheno, A., Rolland, A. et al. A new approach to modelling Kelvin probe force microscopy of hetero-structures in the dark and under illumination. Opt Quant Electron 50, 41 (2018). https://doi.org/10.1007/s11082-017-1305-z
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DOI: https://doi.org/10.1007/s11082-017-1305-z