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Syntheses, Crystal Structures and Theoretical Calculations of Two Nickel, Zinc Coordination Polymers with 4-Nitrophthalic Acid and Bis(imidazol) Ligands

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Abstract

Two new complexes [Ni(4-nph)(bix)(H2O)]n(1) and [Zn(4-nph)(mbix)]n·nH2O (2) (4-H2nph = 4-nitrophthalic acid, bix = 1,4-bis(imidazol-1-yl)-benzene, mbix = 1,3-bis(imidazol-1-yl)-benzene) have been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectroscopy, TG, fluorescence spectroscopy, single-crystal and powder X-ray diffraction. Complex 1 exhibits two dimensional (2D) network structure contain 42-number ring and complex 2 shows one-dimensional ribbon, which were further extended into three-dimensional supramolecular structure through hydrogen bonds and π–π stacking interactions. Moreover, we analyzed the natural bond orbital using the PBE0/LANL2DZ method in the Gaussian 03 program of complexes 1 and 2. The calculation results indicated the obvious covalent interactions between the coordinated atoms and the NiII, ZnII ion respectively.

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References

  1. Y.M. Zhang, S. Yuan, G. Day, X. Wang, X. Yang, H.C. Zhou, Coord. Chem. Rev. 354, 28 (2018)

    Article  CAS  Google Scholar 

  2. L. Mei, W.Q. Shi, Z.F. Chai, Bull. Chem. Soc. Jpn. 91, 554 (2018)

    Article  CAS  Google Scholar 

  3. R. Sakamoto, Bull. Chem. Soc. Jpn. 90, 272 (2017)

    Article  CAS  Google Scholar 

  4. L. Jiao, Y. Wang, H.L. Jiang, Q. Xu, Adv. Mater. 30, 1703663 (2018)

    Article  Google Scholar 

  5. J.S. Hu, L.F. Huang, X.Q. Yao, L. Qin, Y.Z. Li, Z.J. Guo, H.G. Zheng, Z.L. Xue, Inorg. Chem. 50, 2404 (2011)

    Article  CAS  Google Scholar 

  6. R. Cao, D.F. Sun, Y.C. Liang, M.C. Hong, K. Tatsumi, Q. Shi, Inorg. Chem. 41, 2087 (2002)

    Article  CAS  Google Scholar 

  7. P.M. Forster, A.R. Burbank, C. Livage, G. Férey, A.K. Cheetham, Chem. Commun. 33, 368 (2004)

    Article  Google Scholar 

  8. P. Mahata, S. Natarajan, Inorg. Chem. 46, 1250 (2007)

    Article  CAS  Google Scholar 

  9. B. Kesanli, Y. Cui, M.R. Smith, E.W. Bittner, B.C. Bockrath, W.B. Lin, Angew. Chem. Int. Ed. 44, 72 (2005)

    Article  CAS  Google Scholar 

  10. Q. Wu, M.J. Cao, B. Wei, Y. Bai, H. Tian, J. Wang, Q.Y. Liu, G.W. Yang, Inorg. Chem. Commun. 62, 111 (2015)

    Article  CAS  Google Scholar 

  11. Z.T. Wang, S.J. Wang, X.M. Li, Y.R. Pan, Chin. J. Struct. Chem. 37, 467 (2018)

    CAS  Google Scholar 

  12. Z. Zhang, M. Pi, T. Wang, C.M. Jin, J. Mol. Struct. 992, 111 (2011)

    Article  CAS  Google Scholar 

  13. L. Croitor, D. Chisca, E.B. Coropceanu, G.F. Volodina, M.S. Fonari, J. Mol. Struct. 1137, 136 (2017)

    Article  CAS  Google Scholar 

  14. Z. Xing, Q.W. Wang, W. Sui, B. Liu, Chin. J. Struct. Chem. 37, 125 (2018)

    CAS  Google Scholar 

  15. G.F. Li, Y.N. Wang, Q.W. Wang, X.M. Li, J.Y. Ji, Chin. J. Inorg. Chem. 30, 2577 (2014)

    Google Scholar 

  16. X.M. Li, M. Sun, Y.R. Pan, J.Y. Ji, Chin. J. Struct. Chem. 35, 298 (2016)

    CAS  Google Scholar 

  17. G.F. Li, Y.N. Wang, Q.W. Wang, X.M. Li, J.Y. Ji, Y.R. Pan, Chin. J. Inorg. Chem. 31, 183 (2015)

    Article  Google Scholar 

  18. X.M. Li, Z.T. Wang, Y.R. Pan, Q.W. Wang, B. Liu, J. Inorg. Organomet. Polym. Mater. 28, 258 (2018)

    Article  CAS  Google Scholar 

  19. G.M. Sheldrick, SHELXS-97, Programs for X-ray Crystal Structure Solution (University of Göttingen, Göttingen, 1997)

    Google Scholar 

  20. G.M. Sheldrick, SHELXL-97, Programs for X-ray Crystal Structure Refinement (University of Göttingen, Göttingen, 1997)

    Google Scholar 

  21. Y.R. Pan, M. Sun, X.M. Li, Chin. J. Struct. Chem. 34, 710 (2015)

    CAS  Google Scholar 

  22. M. Devereux, D.O. Shea, A. Kellett, M. McCann, M. Walsh, D. Egan, C. Deegan, K. Kędziora, G. Rosair, H. Müller-Bunz, Inorg. Biochem. 101, 881 (2007)

    Article  CAS  Google Scholar 

  23. S. Ruchi, K.P. Bharadwaj, Cryst. Growth Des. 13, 3722 (2013)

    Article  Google Scholar 

  24. X. Bing, J. Xie, H.M. Hu, X.L. Yang, F.X. Dong, M.L. Yang, G.L. Xue, Cryst. Growth Des. 14, 1629 (2014)

    Article  Google Scholar 

  25. Y. Cui, Y. Yue, G. Qian, B. Chen, Chem. Rev. 112, 1126 (2012)

    Article  CAS  Google Scholar 

  26. G.G. Mohamed, N.E.A. El-Gamel, Spectrochim. Acta A 60, 3141 (2004)

    Article  Google Scholar 

  27. U. Mukhopadhyay, I. Bernal, Cryst. Growth Des. 5, 1687 (2005)

    Article  CAS  Google Scholar 

  28. G.L. Li, G.Z. Liu, L.L. Huang, L. Li, X. Zhang, J. Inorg. Organomet. Polym. 24, 617 (2014)

    Article  CAS  Google Scholar 

  29. M.J. Frisch, G.W. Trucks, H.B. Schlegel, G.E. Scuseria, M.A. Robb, J.R. Cheeseman, R.E. Stratmann, O. Yazyev, A.J. Austin, R. Cammi, C. Pomelli, J.W. Ochterski, P.Y. Ayala, K. Morokuma, G.A. Voth, P. Salvador, J.J. Dannenberg, V.G. Zakrzewski, S. Dapprich, A.D. Daniels, M.C. Strain, O. Farkas, D.K. Malick, A.D. Rabuck, K. Raghavachari, J.B. Foresman, J.V. Ortiz, Q. Cui, A.G. Baboul, S. Clifford, J. Cioslowski, B.B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R.L. Martin, D.J. Fox, T. Keith, M.A. AlLaham, C.Y. Peng, A. Nanayakkara, M. Challacombe, P.M.W. Gill, B. Johnson, W. Chen, M.W. Wong, C. Gonzalez, J.A. Pople, Gaussian 03, Revision B.03 (Gaussian Inc, Pittsburgh, PA, 2003)

    Google Scholar 

  30. R.G. Parr, W. Yang, Density Functional Theory of Atoms and Molecules (Oxford University Press, Oxford, 1989)

    Google Scholar 

  31. C. Adamo, V.J. Barone, Chem. Phys. 110, 6158 (1999)

    CAS  Google Scholar 

  32. M. Ernzerhof, G.E. Scuseria, J. Chem. Phys. 110, 5029 (1999)

    Article  CAS  Google Scholar 

  33. L. Wang, J. Zhao, L. Ni, J. Yao, J. Inorg. Gen. Chem. 638, 224 (2012)

    CAS  Google Scholar 

  34. Z.P. Li, Y.H. Xing, Y.H. Zhang, Acta Phys. Chim. Sin. 25, 741 (2009)

    CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the Science and Technology Development Project of Jilin Provincial Science & Technology Department (Grant No. 2015052006JH) and the Science and Technology Research Projects of the Education Department of Jilin Province (Grant No. 2016219). Program supports from State Key Laboratory of Theoretical and Computational Chemistry of Tonghua Normal University are gratefully acknowledged.

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Authors and Affiliations

  1. Faculty of Chemistry, Tonghua Normal University, Tonghua, 134002, China

    Xiu-Mei Li, Zhi-Tao Wang & Ya-Ru Pan

  2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130012, China

    Zhi-Tao Wang, Valentin Valtchev & Qian-Rong Fang

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  1. Xiu-Mei Li
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  2. Zhi-Tao Wang
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  3. Valentin Valtchev
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  4. Qian-Rong Fang
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  5. Ya-Ru Pan
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Correspondence to Valentin Valtchev.

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Li, XM., Wang, ZT., Valtchev, V. et al. Syntheses, Crystal Structures and Theoretical Calculations of Two Nickel, Zinc Coordination Polymers with 4-Nitrophthalic Acid and Bis(imidazol) Ligands. J Inorg Organomet Polym 30, 477–485 (2020). https://doi.org/10.1007/s10904-019-01206-z

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  • DOI: https://doi.org/10.1007/s10904-019-01206-z

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