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Ancillary Ligand-Mediated Syntheses, Structures and Fluorescence of Three Zn/Cd(II) Coordination Polymers Based on Nitrobenzene Dicarboxylate

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Abstract

The Zn/Cd(II)-nbdc carboxylate motifs mediated by various dipyridyl-typed ligands afforded three new coordination compounds, namely, [Zn(nbdc)(bpa)0.5(H2O)]·H2O (1), [Zn2(nbdc)2(bpp)2]·H2O (2), and [Cd(nbdc)(bpe)0.5(H2O)2] (3) (H2nbdc = 4-nitrobenzene-1,2-dicarboxylic acid, bpa = 1,2-bi(4-pyridyl)ethane, bpe = 1,2-di(4-pyridyl)ethylene, and bpp = 1,3-bis(4-pyridyl)propane), which were synthesized by hydrothermal reaction and characterized by elemental analysis, IR, thermal analysis (TGA), and fluorescent analysis. The single-crystal X-ray diffractions reveal that three complexes display a diverse range of connectivity topology from 1D to 3D, which is dependent on the type of dipyridyl-typed ligands and metal centers. Complex 1 is the 1D chain featuring Zn-carboxylate binuclears extended further by bpa coligands. Complex 2 is the 2D thick-layer containing double-stranded chains cross-linked further by bpp coligands. Complex 3 is the 3D framework with (63)(65.8) ins topology featuring Cd-carboxylate chiral layers pillared by bpe coligands. The thermal stabilities and fluorescence properties for complexes 1–3 are investigated.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (Nos. 20971064 and 21071074), the Foundation for University Young Key Teacher by Henan Province of China (Grant No. 2011 GGJS-153) and the Foundation of Science and Technology of Henan Province (Grant No. 112102310638).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, 471022, Henan, People’s Republic of China

    Gui-lian Li, Guang-zhen Liu, Lei-lei Huang, Lin Li & Xue Zhang

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  1. Gui-lian Li
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  2. Guang-zhen Liu
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  4. Lin Li
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Correspondence to Guang-zhen Liu.

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Li, Gl., Liu, Gz., Huang, Ll. et al. Ancillary Ligand-Mediated Syntheses, Structures and Fluorescence of Three Zn/Cd(II) Coordination Polymers Based on Nitrobenzene Dicarboxylate. J Inorg Organomet Polym 24, 617–623 (2014). https://doi.org/10.1007/s10904-014-0024-1

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