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Magnetic solid-phase extraction of triclosan using core-shell Fe3O4@MIL-100 magnetic nanoparticles, and its determination by HPLC with UV detection

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Abstract

The article describes the synthesis of core-shell magnetic nanoparticles (MNPs) of the type Fe3O4@MIL-100 (MIL standing for Material Institut Lavoisier), and their application as sorbent for magnetic solid-phase extraction (MSPE) of triclosan. The MNPs were prepared via circular self-assembly of ferric chloride and benzenetricarboxylic acid. The functionalized MNPs were characterized by transmission electron microscopy, FTIR and thermogravimetry. Following extraction, triclosan was eluted with ammoniacal methanol and then submitted to HPLC with UV detection. The amount of magnetic microspheres, sample pH and ionic strength, adsorption time, desorption time, desorption solvent and the volume of the eluent were optimized. Under optimum conditions, the method showed good linearity in the 0.1 to 50 mg·kg−1 triclosan concentration range in toothpaste samples. Other features include (a) intra-day and inter-day relative standard deviations (RSD, for n = 4) of <5.5 %, (b) a 30 μg·kg−1 limit of detection, and (c) extraction recoveries between 90.86 % and 101.1 %. The method was successfully applied to the determination of triclosan in children’s toothpaste.

The article describes the synthesis of core-shell magnetic nanoparticles (MNPs) of the type Fe3O4@MIL-100, and their application as sorbent for magnetic solid-phase extraction (MSPE) of triclosan.

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Acknowledgments

This work was supported by the Natural Science Fund for Creative Research Groups of Hubei Province of China (grant no. 2011CDA111), the Education Commission of Hubei Province of China (grant no. T201101, D20120106), Educational Commission of Hubei Province of China (grant no. D20120106), and the open fund of Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules (grant no. 020-044159). The authors would like to thank their colleagues for their valuable technical assistance.

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Authors and Affiliations

  1. Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules & College of Chemistry and Chemical Engineering, Hubei University, Wuhan, 430062, China

    Yang Yang, Xiaowei Ma, Fan Feng, Xueping Dang, Jianlin Huang & Huaixia Chen

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  1. Yang Yang
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  2. Xiaowei Ma
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  3. Fan Feng
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Correspondence to Huaixia Chen.

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Yang, Y., Ma, X., Feng, F. et al. Magnetic solid-phase extraction of triclosan using core-shell Fe3O4@MIL-100 magnetic nanoparticles, and its determination by HPLC with UV detection. Microchim Acta 183, 2467–2472 (2016). https://doi.org/10.1007/s00604-016-1872-x

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  • DOI: https://doi.org/10.1007/s00604-016-1872-x

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