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On the stability of defects in the structure of electrochemical coatings

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Abstract

The conditions of metal hydride formation are studied during the cathodic reduction of metals through the parallel reactions of the Men+ and H+ cations. It is established that this interaction is possible not only through the introduction and localization of a hydrogen atom in the metal structure (e.g., in interstices). The hydrides can also be formed in areas of metal structure defects. The energy of hydrogen-metal interaction in metallurgy is shown to be different from that which takes place in electroplating. Thus, we have observed certain mechanisms of hydrogen interaction with electrolytic metals and alloys. We have shown the exceptional role of structural defects in causing the formation of metal-hydrogen bonds. It is found that stable defects can be applied for the accumulation of hydrogen in the form of hydrides.

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Authors and Affiliations

  1. Joint Stock Company of Scientific Engineering Technological Bureau “Ferrit,”, Voronezh State Technical University, ul. Generala Lizyukova 3-248, Voronezh, 394053, Russia

    A. V. Zvyagintseva & Yu. N. Shalimov

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  1. A. V. Zvyagintseva
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  2. Yu. N. Shalimov
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Correspondence to A. V. Zvyagintseva.

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Original Russian Text © A.V. Zvyagintseva, Yu.N. Shalimov, 2014, published in Elektronnaya Obrabotka Materialov, 2014, No. 6, pp. 13–24.

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Zvyagintseva, A.V., Shalimov, Y.N. On the stability of defects in the structure of electrochemical coatings. Surf. Engin. Appl.Electrochem. 50, 466–477 (2014). https://doi.org/10.3103/S106837551406012X

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  • DOI: https://doi.org/10.3103/S106837551406012X

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