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Influence of Chemical Structure on the Thermo-Sensitive Luminescent Properties of Vitrified Films Based on Anisometric Europium(III) Beta-Diketonate Complexes

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Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

Vitrified films are prepared from melt powders of three anisometric europium(III) beta-diketonate complexes. It is shown that varying the aromatic, alicyclic, and aliphatic substituents in the ligand structures strongly affects the temperature dependence of the luminescence decay time of Eu3+ ions, which determines the operational parameters of luminescent temperature probes based on these films.

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Funding

Synthesis of lanthanide complexes and materials based on them was supported by the Russian Science Foundation, project no. 18-13-00112. Spectroscopic measurements were made with the support of the Russian Foundation for Basic Research, projects no. 19-03-00635 and 19-02-00569. The processing and analysis of the experimental data were supported by government assignment for the Federal Research Center “Kazan Scientific Center” of the Russian Academy of Sciences.

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Authors and Affiliations

  1. Zavoisky Physical-Technical Institute, Federal Research Center “Kazan Scientific Center”, Russian Academy of Sciences, 420029, Kazan, Tatarstan, Russia

    D. V. Lapaev, V. G. Nikiforov, V. S. Lobkov & Yu. G. Galyametdinov

  2. Kazan National Research Technological University, 420015, Kazan, Tatarstan, Russia

    R. M. Ziyatdinova, A. A. Knyazev & Yu. G. Galyametdinov

Authors
  1. D. V. Lapaev
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  2. V. G. Nikiforov
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  3. V. S. Lobkov
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  4. R. M. Ziyatdinova
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  5. A. A. Knyazev
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  6. Yu. G. Galyametdinov
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Corresponding author

Correspondence to D. V. Lapaev.

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Translated by N. Saetova

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Lapaev, D.V., Nikiforov, V.G., Lobkov, V.S. et al. Influence of Chemical Structure on the Thermo-Sensitive Luminescent Properties of Vitrified Films Based on Anisometric Europium(III) Beta-Diketonate Complexes. Bull. Russ. Acad. Sci. Phys. 85, 1377–1382 (2021). https://doi.org/10.3103/S1062873821120224

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  • DOI: https://doi.org/10.3103/S1062873821120224

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