Abstract
A new europium(III) chelate is synthesized and characterized. The wavelength of sensitization of Eu3+ luminescence is shifted further into visible so that efficient excitation with 425, 435 and 450-nm LEDs becomes possible. Photophysical properties and temperature dependence of luminescence are investigated in toluene solution and various polymer matrixes. The sensor materials are also characterized in terms of cross-sensitivity to oxygen and photostability. The sensor material based on the europium complex immobilized into poly(vinylidene chloride-co-acrylonitrile) shows negligible cross-sensitivity to oxygen and is particularly attractive for applications at physiological conditions. Other materials can be applied for sensing and imaging purposes at room temperatures. The new materials can also be used for compensating optical (oxygen, CO2 etc.) sensors for temperature effects.
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Berry MT, May PS, Xu H (1996) Temperature dependence of the Eu3+5 D0 lifetime in europium tris(2,2,6,6-tetramethyl-3,5-heptanedionato). J Phys Chem 100(22):9216–9222
Mitsuishi M, Kikuchi S, Miyashita T, Amao Y (2003) Characterization of an ultrathin polymer optode and its application to temperature sensors based on luminescent europium complexes. J Mater Chem 13(12):2875–2879
Khalil GE, Lau K, Phelan GD, Carlson B, Gouterman M, Callis JB, Dalton LD (2004) Europium beta-diketonate temperature sensors: Effects of ligands, matrix, and concentration. Rev Sci Instrum 75(1):192–206
Dadabhoy A, Faulkner S, Sammes PG (2000) Small singlet–triplet energy gap of acridone enables longer wavelength sensitisation of europium(III) luminescence. J Chem Soc Perkin Trans 2(12):2359–2360
Van Deun R, Nockemann P, Fias P, Van Hecke K, Van Meervelt L, Binnemans K (2005) Visible light sensitisation of europium(III) luminescence in a 9-hydroxyphenal-1-one complex. Chem Commun 7:590–592
Yang C, Fu LM, Wang Y, Zhang JP, Wong WT, Ai XC, Qiao YF, Zou BS, Gui LL (2004) A highly luminescent europium complex showing visible-light-sensitized red emission: direct observation of the singlet pathway. Angew Chem Int Ed 43(38):5009–5013
Borisov SM, Wolfbeis OS (2006) Temperature-sensitive europium(III) probes and their use for simultaneous luminescent sensing of temperature and oxygen. Anal Chem 78(14):5094–5101
Liebsch G, Klimant I, Wolfbeis OS (1999) Luminescence lifetime temperature sensing based on sol–gels and poly(acrylonitrile)s dyed with ruthenium metal-ligand complexes. Adv Mater 11(15):1296–1299
Borisov SM, Vasylevska GS, Krause Ch, Wolfbeis OS (2006) Composite luminescent material for dual sensing of oxygen and temperature. Adv Funct Mater 16(12):1536–1542
Koese ME, Carrol BF, Schanze KS (2005) Preparation and spectroscopic properties of multiluminophore luminescent oxygen and temperature sensor films. Langmuir 21(20):9121–9129
Klimant I, Ruckruh F, Liebsch G, Stangelmayer A, Wolfbeis OS (1999) Fast response oxygen micro-optodes based on novel soluble ormosil glasses. Mikrochim Acta 131(1–2):35–46
Golesworthy RC, Shaw RA, Smith BS (1962) 1,3,5-Triazines. part I. The reaction of cyanuric chloride with N,N-diethylaniline. J Chem Soc 1507–1508
Demas JN, Crosby GA (1971) The measurement of photoluminescence quantum yields. J Phys Chem 75(8):991–1024
Bondarev SL, Knyukshto VN, Stepuro VI, Stupak AP, Turbana AA (2004) Fluorescence and electronic structure of the laser dye DCM in solutions and in polymethylmethacrylate. J Appl Spectrosc 71(2):194–201
Cowley DJ, Healy PJ (1979) The fluorescence of some dipolar N,N-Dialkyl-4-(dichloro-1,3,5-triazinyl) anilines. Part 1. Solvent effects and solvent exciplex formation. J Chem Soc Perkin Trans II:485–489
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Borisov, S.M., Klimant, I. Blue LED Excitable Temperature Sensors Based on a New Europium(III) Chelate. J Fluoresc 18, 581–589 (2008). https://doi.org/10.1007/s10895-007-0302-1
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DOI: https://doi.org/10.1007/s10895-007-0302-1