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Influence of the Mechanochemical Modification of Humic Acids on the Formation of Colloids in Solution

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Abstract

The colloid-chemical properties of humic acids (HAs) were studied depending on the mechanochemical modification of their structure. An increase in the amount of acidic ionogenic groups and hydrophilic fragments in the composition of modified HAs facilitated a decrease in the excess energy of surface molecules. In an alkaline solution, two types of colloids characterized by a decrease in the energy of adsorption and the constant of adsorption equilibrium were formed as the concentration of HAs was increased.

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Funding

This work was funded by the Ministry of Science and Higher Education of the Russian Federation and carried out within the framework of a state contract of the Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences.

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Correspondence to N. V. Yudina or A. V. Savel’eva.

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The authors declare that they have no conflicts of interest.

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Translated by V. Makhlyarchuk

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Yudina, N.V., Savel’eva, A.V. Influence of the Mechanochemical Modification of Humic Acids on the Formation of Colloids in Solution. Solid Fuel Chem. 57, 314–318 (2023). https://doi.org/10.3103/S0361521923050075

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  • DOI: https://doi.org/10.3103/S0361521923050075

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