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Development of palladium catalysts on carbon supports from the Sibunit family for vegetable oil hydrogenation processes

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Abstract

Studies on the synthesis of powdered Pd/C catalysts prepared by the supporting of Pd onto a mesoporous carbon material from the Sibunit family and the characterization of their properties in the process of the partial hydrogenation of sunflower oil are reported. The comparative tests of a 1.0 wt % Pd/Sibunit catalyst and Pricat and Nysosel commercial nickel catalysts in the hydrogenation sunflower oil were performed with the use of a Parr batch reactor. It was found that the Pd catalyst was superior to Ni analogs in activity, and it afforded sunflower oil partial hydrogenation products with reproducible characteristics.

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References

  1. Coenen, J.W.E., Ind. Eng. Chem. Fundam., 1986, vol. 25, no. 1, p. 43.

    Article  CAS  Google Scholar 

  2. Rylander, P.N., J. Am. Oil Chem. Soc., 1970, vol. 47, no. 12, p. 482.

    Article  CAS  Google Scholar 

  3. Nohair, B., Especel, C., Lafaye, G., Marecot, P., Hoang, L.C., and Barbier, J., J. Mol. Catal. A, 2005, vol. 229, p. 117.

    Article  CAS  Google Scholar 

  4. Yermakov, Yu.I., Surovikin, V.F., Plaksin, G.V., et al., React. Kinet. Catal. Lett., 1987, vol. 33, no. 2, p. 435.

    Article  CAS  Google Scholar 

  5. Semikolenov, V.A., Simakova, I.L., and Sadovnichii, G.V., Khim. Prom-st., 1996, no. 3, p. 40.

    Google Scholar 

  6. Abdullina, R.M., Voropaev, I.N., Romanenko, A.V., et al., Zh. Prikl. Khim., 2012, vol. 85, no. 8, p. 1265.

    Google Scholar 

  7. Troitskii, S.Yu., Likholobov, V.A., Simonov, P.A., et al., RF Patent No. 1593009, Byull. Izobret., 1999, no. 16.

    Google Scholar 

  8. Heal, G.R. and Mkayula, L.L., Carbon, 1988, vol. 26, no. 6, p. 815.

    Article  CAS  Google Scholar 

  9. GOST (State Standard) 30418-96: Vegetable Oils. Method for the Determination of Fatty Acid Composition, 1996.

  10. GOST (State Standard) R 53605-2009 (EN 14214:2003): Fuel for Internal Combustion Engines. Fatty Acid Methyl Esters (FAME) for Diesels. General Technical Requirements, 2009.

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Correspondence to A. V. Romanenko.

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Original Russian Text © A.V. Romanenko, I.N. Voropaev, R.M. Abdullina, V.A. Chumachenko, 2014, published in Khimiya Tverdogo Topliva, 2014, No. 6, pp. 33–39.

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Romanenko, A.V., Voropaev, I.N., Abdullina, R.M. et al. Development of palladium catalysts on carbon supports from the Sibunit family for vegetable oil hydrogenation processes. Solid Fuel Chem. 48, 356–363 (2014). https://doi.org/10.3103/S0361521914060044

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  • DOI: https://doi.org/10.3103/S0361521914060044

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