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Effect of the Nature of Supports and the Degree of Palladium Dispersion on the Catalyst Activity and Selectivity in the Sunflower Oil Hydrogenation Reaction

  • CATALYSIS IN CHEMICAL AND PETROCHEMICAL INDUSTRY
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Abstract

Results of studying the Pd/C and Pd/O powder catalysts synthesized by the deposition of 0.5 and 1.0 wt % Pd on carbon materials (Sibunit 159k, thermal carbon black T-900, Vulcan XC-72R) and oxide supports (Ox: γ-Al2O3, Cr2O3, Ga2O3, TiO2, Ta2O5, and V2O5, diatomaceous earth FW-70) and their catalytic properties in the partial hydrogenation of sunflower oil were described. Using a Parr fixed-bed reactor, comparative tests of the catalysts in the kinetic mode conducted to determine their activity (SCA, V0) and trans-isomerization selectivity parameters (Str). The effect of the average particle size of supported palladium (dCO) on these parameters in a wide range of dCO values was discussed.

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Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation under a state task to Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences (project no. AAAA-A21-121011390055-8).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    A. V. Romanenko & G. A. Bukhtiyarova

  2. Novosibirsk State University, 630090, Novosibirsk, Russia

    P. A. Simonov & M. A. Kulagina

  3. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 664033, Irkutsk, Russia

    S. I. Udalova

  4. OOO NIOST, 634067, Tomsk, Russia

    I. N. Voropaev

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  1. A. V. Romanenko
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Romanenko, A.V., Simonov, P.A., Kulagina, M.A. et al. Effect of the Nature of Supports and the Degree of Palladium Dispersion on the Catalyst Activity and Selectivity in the Sunflower Oil Hydrogenation Reaction. Catal. Ind. 15, 374–386 (2023). https://doi.org/10.1134/S2070050423040098

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