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SiO2-modified MIL-53 for enhanced adsorption of chlorpyriphos from aqueous solutions: Synthesis, characterization, and mechanistic insights

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Abstract

Chlorpyriphos an organophosphorus pesticide, is readily absorbed through the skin of humans and poses the serious risk. In present study the surface modification of Fe-based metal organic framework (MIL-153) was carried out with silica for studying its efficiency toward adsorptive removal of Chlorpyriphos. For studying the physico-chemical properties of MIL-53/SiO2 composite various characterization techniques like FTIR, BET, FE-SEM, EDS, XRD, and PSA were utilized. The effect of most significant parameters was optimized, and maximum removal of 60% was observed at pH 6. The monolayer adsorption onto energetically equivalent sorption sites described the chlorpyriphos capture by MIL-53/SiO2. The maximum adsorptive capacity obtained by the non-linear Langmuir model was 58.5 mg chlorpyriphos per g MIL-53/SiO2. Additionally, the kinetic models revealed the dependence of rate on the adsorptive capacity of adsorbent.

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Acknowledgments

The author thanks Residue Analysis Lab, College of Agriculture, CCSHAU, Hisar for providing chlorpyriphos; Centre for Bio-Nano Technology, CCSHAU, Hisar and Indian Institute of Technology, Roorkee for help in characterization.

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Authors and Affiliations

  1. Department of Chemistry, Chaudhary Charan Singh Haryana Agricultural University Hisar, Haryana, 125001, India

    Prachi Sharma, Anushree Jatrana, Sanchit Mondal & Sheetal Maan

  2. Department of Physics, Chaudhary Charan Singh Haryana Agricultural University Hisar, Haryana, 125001, India

    Vinay Kumar

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  1. Prachi Sharma
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Contributions

Prachi Sharma: writing—original draft, Investigation. Anushree Jatrana: resources, writing—review & editing, supervision. Vinay Kumar: formal analysis, data curation. Sanchit Mondal: conceptualization, validation. Sheetal Maan: methodology.

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Correspondence to Anushree Jatrana.

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Sharma, P., Jatrana, A., Kumar, V. et al. SiO2-modified MIL-53 for enhanced adsorption of chlorpyriphos from aqueous solutions: Synthesis, characterization, and mechanistic insights. Journal of Materials Research (2024). https://doi.org/10.1557/s43578-024-01315-7

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