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Ceramic Membranes Prepared from a Silicate and Clay-mineral Mixture for Treatment of Oily Wastewater

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Clays and Clay Minerals

Abstract

The application of ceramic membranes is limited by the high cost of raw materials and the sintering process at high temperatures. To overcome these drawbacks, the present study investigated both the preparation of ceramic membranes using cost-effective raw materials and the possibility of recycling the membranes for the treatment of oily wastewater. Ceramic membranes with a pore size of 0.29–0.67 μm were prepared successfully at temperatures as low as 1000–1100°C by a simple pressing route using lowcost base materials including diatomite, kaolin, bentonite, talc, sodium borate, and barium carbonate. The typical steady-state flux, fouling resistance, and oil-rejection rate of the low-cost virgin membranes sintered at 1000°C were 2.5 × 10−5 m3m−2s−1 at 303 kPa, 63.5%, and 84.1%, respectively, with a feed oil concentration of 600 mg/L. A simple burn-out process of the used membranes at 600°C in air resulted in >95% recovery of the specific surface area (SSA) of the virgin membranes, a significantly increased steady-state flux, decreased fouling resistance, and increased oil-rejection rate. The typical steady-state flux, fouling resistance, and oil-rejection rate of the low-cost ceramic membrane sintered at 1000°C and subsequently heat treated at 600°C for 1 h in air after the first filtration were 5.4 × 10−5 m3m−2s−1 at 303 kPa, 27.1%, and 92.9%, respectively, with a feed oil concentration of 600 mg/L. The present results suggest that the low-cost ceramic membranes used for oily wastewater filtration can be recycled by simple heat-treatment at 600°C in air. As the fouling resistance of the low-cost ceramic membranes decreased with a decrease in pore size, the preferred pore size of the membranes for oily wastewater filtration is <0.4 μm.

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References

  • Abadi, S.R.H., Sebzari, M.R., Hemati, M., Rekabdar, F., and Mohammadi, T. (2011) Ceramic membrane performance in microfiltration of oily wastewater. Desalination, 265, 222–228.

    Article  Google Scholar 

  • Abbasi, M., Mirfendereski, M., Nikbakht, M., Golshenas, M., and Mohammadi, T. (2010) Performance study of mullite and mullite—alumina ceramic MF membranes for oily wastewaters treatment. Desalination, 259, 169–178.

    Article  Google Scholar 

  • Belibi, P.B., Nguemtchouin, M.M.G., Rivallin, M., Nsami, J.N., Sieliechi, J., Cerneaux, S., Ngassoum, M.B., and Cretin, M. (2015) Microfiltration ceramic membranes from local Cameroonian clay applicable to water treatment. Ceramics International, 41, 2752–2759.

    Article  Google Scholar 

  • Belkacem, M., Bahlouli, M., Mraoui, A., and Bensadok, K. (2007) Treatment of oil-water emulsion by ultrafiltration: a numerical approach. Desalination, 206, 433–439.

    Article  Google Scholar 

  • Bouzerara, F., Harabi, A., Achour, S., and Larbot, A. (2006) Porous ceramic supports for membranes prepared from kaolin and doloma mixtures. Journal of the European Ceramic Society, 26, 1663–1671.

    Article  Google Scholar 

  • Chen, W., Peng, J., Su, Y., Zheng, L., Wang, L., and Jiang, Z. (2009) Separation of oil/water emulsion using Pluronic F127 modified polyethersulfone ultrafiltration membranes. Separation and Purification Technology, 66, 591–597.

    Article  Google Scholar 

  • Cheryan, M. and Rajagopalan, N. (1998) Membrane processing of oily streams. Wastewater treatment and waste reduction. Journal of Membrane Science, 151, 13–28.

    Article  Google Scholar 

  • Emani, S., Uppaluri, R., and Purkait, M.K. (2013) Preparation and characterization of low cost ceramic membranes for mosambi juice clarification. Desalination, 317, 32–40.

    Article  Google Scholar 

  • Emani, S., Uppaluri, R., and Purkait, M.K. (2014) Microfiltration of oil-water emulsions using low cost ceramic membranes prepared with the uniaxial dry compaction method. Ceramics International, 40, 1155–1164.

    Article  Google Scholar 

  • Eom, J.H. and Kim, Y.W. (2008) Effect of template size on microstructure and strength of porous silicon carbide ceramics. Journal of the Ceramic Society of Japan, 116, 1159–1163.

    Article  Google Scholar 

  • Eom, J.H., Kim, Y.W., Song, I.H., and Kim, H.D. (2008) Processing and properties of polysiloxane-derived porous silicon carbide ceramics using hollow microspheres as templates. Journal of the European Ceramic Society, 28, 1029–1035.

    Article  Google Scholar 

  • Eom, J.H., Kim, Y.W., and Raju, S. (2013a) Processing and properties of macroporous silicon carbide ceramics: A review. Journal of Asian Ceramic Societies, 1, 220–242.

    Article  Google Scholar 

  • Eom, J.H., Kim, Y.W., and Song, I.H. (2013b) Processing of kaolin-based microfiltration membranes. Journal of the Korean Ceramic Society, 50, 341–347.

    Article  Google Scholar 

  • Eom, J.-H., Kim, Y.-W., Yun, S.-H., and Song, I.-H. (2014) Low-cost clay-based membranes for oily wastewater treatment. Journal of the Ceramic Society of Japan, 122, 788–794.

    Article  Google Scholar 

  • Ezzati, A., Gorouhi, E., and Mohammadi, T. (2005) Separation of water in oil emulsions using microfiltration. Desalination, 185, 371–382.

    Article  Google Scholar 

  • Gorouhi, E., Sadrzadeh, M., and Mohammadi, T. (2006) Microfiltration of oily wastewater using PP hydrophobic membrane. Desalination, 200, 319–321.

    Article  Google Scholar 

  • Ha, J., Oh, E., and Song, I. (2013a) The effect of sacrificial templates on the pore characteristics of sintered diatomite membranes. Journal of the Ceramic Society of Japan, 121, 940–945.

    Article  Google Scholar 

  • Ha, J.-H., Oh, E., Ahmad, R., and Song, I.-H. (2013b) The effects of pore structures on the air permeation properties of sintered diatomite. Ceramics International, 39, 3881–3884.

    Article  Google Scholar 

  • Hajasgarkhani, M.A., Mousavi, S.M., and Saljoughi, E. (2013) Effects of coagulation-bath temperature and montmorillonite nanoclay content on asymmetric cellulose acetate butyrate membranes. Clays and Clay Minerals, 61, 541–550.

    Article  Google Scholar 

  • Harabi, A., Zenikheri, F., Boudaira, B., Bouzerara, F., Guechi, A., and Foughali, L. (2014) A new and economic approach to fabricate resistant porous membrane supports using kaolin and CaCO3. Journal of the European Ceramic Society, 34, 1329–1340.

    Article  Google Scholar 

  • Khemakhem, S., Larbot, A., and Ben Amar, R. (2006) Study of performances of ceramic microfiltration membrane from Tunisian clay applied to cuttlefish effluents treatment. Desalination, 200, 307–309.

    Article  Google Scholar 

  • Kim, Y.W., Eom, J.H., Wang, C., and Park, C.B. (2008) Processing of porous silicon carbide ceramics from carbon-filled polysiloxane by extrusion and carbothermal reduction. Journal of the American Ceramic Society, 91, 1361–1364.

    Article  Google Scholar 

  • Kroll, S., Treccani, L., Rezwan, K., and Grathwohl, G. (2010) Development and characterisation of functionalised ceramic microtubes for bacteria filtration. Journal of Membrane Science, 365, 447–455.

    Article  Google Scholar 

  • Kumara, S.M. and Roy, S. (2008) Filtration characteristics in dead-end microfiltration of living Saccharomyces cerevisiae cells by alumina membranes. Desalination, 229, 348–361.

    Article  Google Scholar 

  • Lee, Y.I., Eom, J.H., Kim, Y.W., and Song, I.H. (2014) Effect of clay-mineral composition on flexural strength of claybased membranes. Journal of the Korean Ceramic Society, 51, 380–385.

    Article  Google Scholar 

  • Li, L., Ding, L., Tu, Z., Wan, Y., Clausse, D., and Lanoiselle, J.L. (2009) Recovery of linseed oil dispersed within an oil-in-water emulsion using hydrophilic membrane by rotating disk filtration system. Journal of Membrane Science, 342, 70–79.

    Article  Google Scholar 

  • Lim, K.Y., Kim, Y.W., and Song, I.H. (2013) Porous sodium borate-bonded SiC ceramics. Ceramics International, 39, 6827–6834.

    Article  Google Scholar 

  • Manoj Kumar, B.V. and Kim, Y.W. (2010) Processing of polysiloxane-derived porous ceramics: a review. Science and Technology of Advanced Materials, 11, 044303.

    Article  Google Scholar 

  • Mohammadi, T., Pak, A., Karbassian, M., and Golshan, M. (2004) Effect of operating conditions on microfiltration of an oil-water emulsion by a kaolin membrane. Desalination, 168, 201–205.

    Article  Google Scholar 

  • Mueller, J., Cen, Y., and Davis, R.H. (1997) Crossflow microfiltration of oily water. Journal of Membrane Science, 129, 221–235.

    Article  Google Scholar 

  • Pagidi, A., Saranya, R., Arthanareeswaran, G., Ismail, F., and Matsuura, T. (2014) Enhanced oil—water separation using polysulfone membranes modified with polymeric additives. Desalination, 344, 280–288.

    Article  Google Scholar 

  • Ratlege, C. (1992) Mini review compilation. Biodegradation and biotransformations of oils and fats — introduction. Journal of Chemical Technology and Biotechnology, 55, 397–398.

    Article  Google Scholar 

  • Saffaj, N., Persin, M., Younsi, S.A., Albizane, A., Cretin, M., and Larbot, A. (2006) Elaboration and characterization of microfiltration and ultrafiltration membranes deposited on raw support prepared from natural Moroccan clay: Application to filtration of solution containing dyes and salts. Applied Clay Science, 31, 110–119.

    Article  Google Scholar 

  • Sahnoun, R.D. and Baklouti S. (2013) Characterization of flat ceramic membrane supports prepared with kaolin-phosphoric acid-starch. Applied Clay Science, 83–84, 399–404.

    Article  Google Scholar 

  • Salahi, A., Gheshlaghi, A., Mohammadi, T., and Madaeni, S.S. (2010a) Experimental performance evaluation of polymeric membranes for treatment of an industrial oily wastewater. Desalination, 262, 235–242.

    Article  Google Scholar 

  • Salahi, A., Abbasi, M., and Mohammadi, T. (2010b) Permeate flux decline during UF of oily wastewater: Experimental and modeling. Desalination, 251, 153–160.

    Article  Google Scholar 

  • Scott, K., Adhamy, A., Atteck, W., and Davidson, C. (1994) Crossflow microfiltration of organic/water suspensions. Water Research, 28, 137–145.

    Article  Google Scholar 

  • Scott, K., Jachuck, R.J., and Hall, D. (2001) Crossflow microfiltration of water-in-oil emulsions using corrugated membranes. Separation and Purification Technology, 22–23, 431–441.

    Article  Google Scholar 

  • Shackelford, C.D. and Lee, J.M. (2003) The destructive role of diffusion on clay membrane behavior. Clays and Clay Minerals, 51, 186–196.

    Article  Google Scholar 

  • Song, C., Wang, T., Pan, Y., and Qiu, J. (2006) Preparation of coal-based microfiltration carbon membrane and application in oily wastewater treatment. Separation and Purification Technology, 51, 80–84.

    Article  Google Scholar 

  • Vasanth, D., Pugazhenthi, G., and Uppaluri, R. (2011a) Fabrication and properties of low cost ceramic microfiltration membranes for separation of oil and bacteria from its solution. Journal of Membrane Science, 379, 154–163.

    Article  Google Scholar 

  • Vasanth, D., Uppaluri, R., and Pugazhenthi, G. (2011b) Influence of sintering temperature on the properties of porous ceramic support prepared by uniaxial dry compaction method using low-cost raw materials for membrane applications. Separation Science and Technology, 46, 1241–1249.

    Article  Google Scholar 

  • Vasanth, D., Pugazhenthi, G., and Uppaluri, R. (2013) Crossflow microfiltration of oil-in-water emulsions using low cost ceramic membranes. Desalination, 320, 86–95.

    Article  Google Scholar 

  • Weir, M.R., Rutinduka, E., Detellier, C., Feng, C.Y., Wang, Q., Matsuura, T., and Mao, R. Le Van (2001) Fabrication, characterization and preliminary testing of all-inorganic ultrafiltration membranes composed entirely of a naturally occurring sepiolite clay mineral. Journal of Membrane Science, 182, 41–50.

    Article  Google Scholar 

  • Zhang, Y., Jin, Z., Wang, Y., and Cui, P. (2010) Study on phosphorylated Zr-doped hybrid silicas/PSF composite membranes for treatment of wastewater containing oil. Journal of Membrane Science, 361, 113–119.

    Article  Google Scholar 

  • Zhou, J., Chang, Q., Wang, Y., Wang, J., and Meng, G. (2010) Separation of stable oil—water emulsion by the hydrophilic nano-sized ZrO2 modified Al2O3 microfiltration membrane. Separation and Purification Technology, 75, 243–248.

    Article  Google Scholar 

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Authors and Affiliations

  1. Functional Ceramics Laboratory, Department of Materials Science and Engineering, The University of Seoul, 163 Seoulsiripdae-ro, Dongdaemun-gu, Seoul, 130-743, Korea

    Jung-Hye Eom, Hee-Jong Yeom & Young-Wook Kim

  2. Engineering Ceramics Group, Korea Institute of Materials Science, 531 Changwondaero, Changwon, Gyeongnam, 641-831, Korea

    In-Hyuck Song

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  1. Jung-Hye Eom
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  2. Hee-Jong Yeom
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  3. Young-Wook Kim
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  4. In-Hyuck Song
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Correspondence to Young-Wook Kim.

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Eom, JH., Yeom, HJ., Kim, YW. et al. Ceramic Membranes Prepared from a Silicate and Clay-mineral Mixture for Treatment of Oily Wastewater. Clays Clay Miner. 63, 222–234 (2015). https://doi.org/10.1346/CCMN.2015.0630305

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  • DOI: https://doi.org/10.1346/CCMN.2015.0630305

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