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Synthesis of Pd−Rh Bimetallic Nanoparticles with Different Morphologies in Reverse Micelles and Characterization of Their Catalytic Properties

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Abstract—

Synthesis of bimetallic nanoparticles (NPs) of the transition metals Rh and Pd in H2O/AOT/isooctane (where AOT is dioctyl sodium sulfosuccinate) reverse-micelle solutions (RMSs) in the presence of molecular oxygen and quercetin, a flavonoid, is described. The methods for NP synthesis used here enable us to prepare alloyed-type Rh−Pd NPs and core/shell Pd/Rh and Rh/Pd NPs with the metal molar ratio of 1 : 1. With both Rh3+ and Pd2+ ions present in an RMS simultaneously, palladium ions are reduced first, and the formed Pd NPs have an inhibitive effect on reduction of rhodium ions. The stability of a mixture of Rh and Pd NPs in RMSs is investigated, and the mixture of NPs with a mean diameter of ~2.7 nm is found to be stable for at least 25 days. Pd and Rh NP-based catalysts are prepared by absorption of the synthesized NPs on γ-Al2O3, and their catalytic activity is tested in the monomolecular hydrogen isotope exchange reaction. A synergetic effect, manifested as an enhanced catalytic activity, is observed for the catalyst prepared by adsorption of the mixture of Rh and Pd NPs on γ-Al2O3.

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ACKNOWLEDGMENTS

Nanoparticle size measurements were performed using the facilities of the Center for Collective Use Physical Methods of Investigations, Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences.

Funding

This work was supported by the Russian Foundation for Basic Research, projects nos. 11-03-90738 and 09-08-00758.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Moscow, Russia

    M. O. Sergeev, A. A. Revina & V. I. Zolotarevskii

  2. D. Mendeleev University of Chemical Technology, Moscow, Russia

    A. A. Revina, O. A. Boeva & K. N. Zhavoronkova

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  1. M. O. Sergeev
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Correspondence to A. A. Revina.

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Sergeev, M.O., Revina, A.A., Boeva, O.A. et al. Synthesis of Pd−Rh Bimetallic Nanoparticles with Different Morphologies in Reverse Micelles and Characterization of Their Catalytic Properties. Prot Met Phys Chem Surf 56, 63–74 (2020). https://doi.org/10.1134/S2070205120010207

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