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The Influence of High Reactivity of Diaryl Telluroxides on Their Chromatography/Mass Spectrometry Identification Data

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Abstract—

The identification features of symmetric and nonsymmetric diaryl telluroxides via chromatography/mass spectrometry with electrospray ionization (HPLC/MS-ESI) are studied in the present work. Diaryl telluroxides exposed to ESI are shown to give rise to the formation of dimer ions and associate ions with the mobile phase components. Moreover, the influence of analyte concentration in the solution and the injection volume is found to impact the chromatography/mass spectrometry data.

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REFERENCES

  1. Srivastava, K., Panda, A., Sharma, S., and Singh, H.B., J. Organomet. Chem., 2018, vol. 861, p. 174.

    Article  CAS  Google Scholar 

  2. Petragnani, N., Tellurium in Organic Synthesis, London: Academic Press, 2007.

    Book  Google Scholar 

  3. Bruins, A.P., Mass Spectrom. Rev., 1991, vol. 10, no. 1, p. 53.

    Article  CAS  Google Scholar 

  4. Eliseeva, E.V., Red’kin, N.A., Gar’kin, V.P., Pytskii, I.S., and Buryak, A.K., Prot. Met. Phys. Chem. Surf., 2015, vol. 51, no. 6, p. 1050.

    Article  CAS  Google Scholar 

  5. Sorokin, A.A., Gar’kin, V.P., Red’kin, N.S., and Buryak, A.K., Russ. J. Appl. Chem., 2010, vol. 83, no. 12, p. 2163.

    Article  CAS  Google Scholar 

  6. Gar’kin, V.P., Rodina, T.A., Solovova, N.B., and Buryak, A.K., Russ. J. Phys. Chem. A, 2008, vol. 82, no. 6, p. 881.

    Article  Google Scholar 

  7. Eliseeva, E.V., Sorokin, A.A., Red’kin, N.A., and Gar’kin, V., Sorbtsionnye Khromatogr.Protsessy, 2014, vol. 14, no. 4, p. 621.

    CAS  Google Scholar 

  8. Irgolic, K.J., Organotellurium Compounds, Stuttgart: Georg Thieme Verlag, 1990.

    Google Scholar 

Download references

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Authors and Affiliations

  1. Korolev Samara National Research University, 443086, Samara, Russia

    E. V. Eliseeva, N. A. Red’kin & V. P. Gar’kin

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    I. S. Pytskii & A. K. Buryak

Authors
  1. E. V. Eliseeva
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  2. N. A. Red’kin
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  3. V. P. Gar’kin
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  4. I. S. Pytskii
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  5. A. K. Buryak
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Correspondence to E. V. Eliseeva.

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Translated by O. Maslova

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Eliseeva, E.V., Red’kin, N.A., Gar’kin, V.P. et al. The Influence of High Reactivity of Diaryl Telluroxides on Their Chromatography/Mass Spectrometry Identification Data. Prot Met Phys Chem Surf 55, 1242–1248 (2019). https://doi.org/10.1134/S2070205119060108

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  • DOI: https://doi.org/10.1134/S2070205119060108

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